{"id":"W2512587412","doi":"10.1021/acs.organomet.5b00322","title":"Rhodium-Catalyzed Selective Partial Hydrogenation of Alkynes","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Engineering and Physical Sciences Research Council; University of Oxford; Canada Foundation for Innovation","keywords":"Chemistry; Alkyne; Rhodium; Alkene; Catalysis; Medicinal chemistry; Hydrogen; Cyclooctene; Oxidative addition; Fluorobenzene; Triethylamine; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002469092,0.0001551213,0.0002707326,0.0001919,0.00004442127,0.00002050277,0.0002350673,0.0001234057,0.0008571786],"category_scores_gemma":[0.00042507,0.0001517177,0.0001237975,0.001140315,0.00006888567,0.0001608267,0.00006717897,0.0001005229,0.0001849158],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001169041,"about_ca_system_score_gemma":0.000148581,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003232402,"about_ca_topic_score_gemma":0.000007376775,"domain_scores_codex":[0.9987076,0.00002230548,0.0003565974,0.0002578888,0.0004550085,0.0002006111],"domain_scores_gemma":[0.998923,0.00005123379,0.0002288387,0.0003155577,0.0003052297,0.0001761102],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000264145,0.001855927,0.01914867,0.0002470134,0.001973078,0.00002748812,0.006335905,0.001003153,0.8970314,0.009957618,0.003167206,0.05898841],"study_design_scores_gemma":[0.0007767298,0.00001616207,0.00009056665,0.000004147352,0.0001261275,0.000008465917,0.0003749561,0.001756888,0.9821822,0.0003663216,0.0140901,0.0002073448],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9464151,0.000337689,0.001719319,0.0001454589,0.00008509341,0.00006968069,0.00003882177,0.0001203947,0.0510685],"genre_scores_gemma":[0.9974769,0.00002201463,0.0003336255,0.000028016,0.0001057542,0.0000134476,0.0002416463,0.0000278875,0.001750744],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08515081,"threshold_uncertainty_score":0.9385505,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02407733344568576,"score_gpt":0.2476376475593611,"score_spread":0.2235603141136753,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}