{"id":"W2512760480","doi":"10.15278/isms.2016.tf05","title":"FTIR SYNCHROTRON SPECTROSCOPY OF THE ASYMMETRIC C-H STRETCHING BANDS OF METHYL MERCAPTAN (CH3SH) – A PERPLEXITY OF PERTURBATIONS","year":2016,"lang":"en","type":"article","venue":"","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of New Brunswick","funders":"","keywords":"Perplexity; Synchrotron; Fourier transform infrared spectroscopy; Spectroscopy; Materials science; Chemistry; Physics; Optics; Computer science; Astronomy; Speech recognition","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001818974,0.000267154,0.0001335655,0.0002282101,0.0002360597,0.0001078368,0.0002328981,0.0001829706,0.002119828],"category_scores_gemma":[0.0001658348,0.0001108481,0.0001399689,0.000380996,0.0001670663,0.0001772565,0.0001479386,0.0004926426,0.0002829128],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002291606,"about_ca_system_score_gemma":0.0002335949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001805782,"about_ca_topic_score_gemma":0.002261087,"domain_scores_codex":[0.9998909,0.00001001205,0.000003869794,0.0000180987,0.0000529645,0.0000242662],"domain_scores_gemma":[0.999881,0.00002229927,0.00002740977,0.00001342795,0.00003758496,0.0000182565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005022425,0.000004991053,0.0002781611,0.000008334696,0.000002025949,0.000009684095,0.00001399809,0.00004917318,0.9986745,0.00004393486,0.00004387494,0.0008210027],"study_design_scores_gemma":[0.000005600559,0.00008036862,0.0227499,0.000003738177,0.000006584029,0.0001029003,0.00005671791,0.001533368,0.9741015,0.000064958,0.001288682,0.000005593118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922799,0.0002869028,0.004704122,0.00006433591,0.00001418187,0.000008201459,0.0008051179,0.00007289783,0.001764396],"genre_scores_gemma":[0.9912033,0.0002628129,0.003950651,0.00004045227,0.000003986651,0.00001577136,0.001350239,0.00002948499,0.003143164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002119828,"threshold_uncertainty_score":0.007091582,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006764605991126396,"score_gpt":0.2362336890007709,"score_spread":0.2294690830096445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}