{"id":"W2513533598","doi":"10.1021/acs.inorgchem.5b02087","title":"Intramolecular C–C Bond Coupling of Nitriles to a Diimine Ligand in Group 7 Metal Tricarbonyl Complexes","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Diimine; Intramolecular force; Ligand (biochemistry); Group (periodic table); Metal; Coupling (piping); Photochemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000402101,0.0002494726,0.0004583367,0.00007471084,0.00002645507,0.00002813523,0.0003284979,0.0001858756,0.0005588999],"category_scores_gemma":[0.001309444,0.0002784972,0.00009464329,0.0006926215,0.00009192212,0.00006162528,0.0002063408,0.0002434488,0.00001295911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002466356,"about_ca_system_score_gemma":0.0001977994,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00011634,"about_ca_topic_score_gemma":0.00001548674,"domain_scores_codex":[0.9981583,0.000006873189,0.0006335534,0.0004338459,0.0004798477,0.0002875655],"domain_scores_gemma":[0.9986761,0.000195479,0.000187602,0.0005093911,0.00017457,0.0002568947],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008704681,0.0001692077,0.003393913,0.0002069384,0.00005114372,0.00001936559,0.0002290569,0.0002189877,0.9950124,0.0000709028,0.0004199356,0.0001211131],"study_design_scores_gemma":[0.001347708,0.00001506158,0.0002394727,0.00008321703,0.00005796097,0.0000527655,0.0005332973,0.000654529,0.9946507,0.0003742611,0.001707883,0.0002831751],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933594,0.000574095,0.001367542,0.0000995518,0.00007273316,0.0000841599,0.00004749458,0.00007515029,0.004319879],"genre_scores_gemma":[0.9970741,0.00000724411,0.001851386,0.00006207219,0.0002197141,0.00002052183,0.0001724607,0.00004813839,0.0005443083],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003775571,"threshold_uncertainty_score":0.9999667,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02596139638954184,"score_gpt":0.2724290212843792,"score_spread":0.2464676248948374,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}