{"id":"W2515164856","doi":"10.1103/physreve.95.033303","title":"Theory of linear sweep voltammetry with diffuse charge: Unsupported electrolytes, thin films, and leaky membranes","year":2017,"lang":"en","type":"article","venue":"Physical review. E","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Linear sweep voltammetry; Cyclic voltammetry; Electrolyte; Dimensionless quantity; Debye length; Diffusion; Voltammetry; Chemistry; Analytical Chemistry (journal); Context (archaeology); Materials science; Electrode; Thermodynamics; Electrochemistry; Ion; Physical chemistry; Physics; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001019419,0.001158582,0.001288208,0.001383592,0.0005065413,0.001498305,0.003072097,0.002597559,0.003010368],"category_scores_gemma":[0.002412065,0.000640701,0.0007879437,0.001006991,0.001649266,0.003196414,0.0009998741,0.002316071,0.001230246],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001299209,"about_ca_system_score_gemma":0.0007548307,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008564325,"about_ca_topic_score_gemma":0.000437231,"domain_scores_codex":[0.9993037,0.0001453886,0.00003823635,0.0001067566,0.0003573064,0.0000486401],"domain_scores_gemma":[0.9994742,0.0002714581,0.00004565407,0.00007426171,0.0001173635,0.0000171296],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.00002473029,0.0000672747,0.0002264166,0.000776603,0.00004537934,0.0003904809,0.0002301873,0.1084527,0.01842002,0.8436305,0.004464637,0.02327103],"study_design_scores_gemma":[0.00001451085,0.00006335696,0.0003383557,0.0001337001,0.00002004618,0.0005336287,0.00004969588,0.5372075,0.00707237,0.4311185,0.02339122,0.00005708691],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.01498104,0.01929862,0.9252775,0.00234909,0.0004577588,0.0002077885,0.0004403475,0.0004458922,0.03654193],"genre_scores_gemma":[0.5573694,0.07070716,0.3010301,0.003633871,0.001000242,0.001633669,0.0007226751,0.0004332646,0.06346971],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.003072097,"threshold_uncertainty_score":0.01007068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01179771944919265,"score_gpt":0.2878868843768003,"score_spread":0.2760891649276077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}