{"id":"W2515387739","doi":"10.1021/acs.organomet.5b00346","title":"Cobalt-Mediated η<sup>5</sup>-Pentadienyl/Alkyne [5 + 2] Cycloaddition Reactions: Substitution Effects, Bicyclic Synthesis, and Photochemical η<sup>4</sup>-Cycloheptadiene Demetalation","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Chemistry; Bicyclic molecule; Cycloaddition; Nucleophile; Alkyne; Isomerization; Nucleophilic addition; Medicinal chemistry; Substituent; Photochemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001127735,0.0003412246,0.0001953326,0.0001251114,0.0001370103,0.0002943248,0.0002534034,0.0001844649,0.001172274],"category_scores_gemma":[0.0001502778,0.0001491311,0.0001619096,0.0001832663,0.0002115373,0.0002393694,0.0002628804,0.0003264488,0.0003426126],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004786217,"about_ca_system_score_gemma":0.0003271371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001026309,"about_ca_topic_score_gemma":0.002556231,"domain_scores_codex":[0.9998674,0.00001189393,0.00001089187,0.00003264148,0.00002716971,0.00005003684],"domain_scores_gemma":[0.9999354,0.00000990852,0.00002133827,0.00001036045,0.00000913204,0.00001385948],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001324675,0.00003706061,0.0002152831,0.0001385481,0.00001466328,0.0001433608,0.00005436995,0.0003596399,0.9889355,0.001042464,0.0001736386,0.008752993],"study_design_scores_gemma":[0.000006425455,0.00009930159,0.0004929233,0.000002702962,0.000008641688,0.0001052482,0.00001007371,0.0003721676,0.9970072,0.00003308312,0.001856969,0.000005339019],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9650989,0.002269761,0.0176938,0.000136993,0.0000779238,0.00009789291,0.0001997354,0.0003083892,0.01411663],"genre_scores_gemma":[0.991173,0.0007093773,0.005510574,0.00003795105,0.000006318494,0.00002069397,0.00009785943,0.00003064735,0.002413662],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001172274,"threshold_uncertainty_score":0.003921628,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01595738016688459,"score_gpt":0.2319523849272641,"score_spread":0.2159950047603795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}