{"id":"W2515536507","doi":"10.1016/j.chroma.2016.08.059","title":"Capillary gas chromatographic separation of organic bases using a pH-adjusted basic water stationary phase","year":2016,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chromatography; Ammonium hydroxide; Analyte; Elution; Selectivity; Capillary action; Volatility (finance); Organic base; Sodium hydroxide; Flame ionization detector; Capillary electrochromatography; Gas chromatography; Phase (matter); Base (topology); Analytical Chemistry (journal); Stationary phase; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00035397,0.000429536,0.0007997793,0.0006804715,0.0001547245,0.00004132469,0.0004412901,0.0002720679,0.00356393],"category_scores_gemma":[0.00007404257,0.0002720785,0.001004991,0.0008990609,0.0004697233,0.0006250523,0.0000619838,0.0002701592,0.000008186657],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005783405,"about_ca_system_score_gemma":0.0001886057,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007865278,"about_ca_topic_score_gemma":0.000002977304,"domain_scores_codex":[0.9966831,0.00007969879,0.001523706,0.0003412969,0.0008533354,0.0005188356],"domain_scores_gemma":[0.9973226,0.0002231432,0.001032262,0.0004692919,0.0006085018,0.000344237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003207437,0.0007439893,0.01312384,0.0004949884,0.0007140591,0.0001440325,0.0001763025,0.000008561512,0.9831178,0.00007182241,0.0006663447,0.0004175444],"study_design_scores_gemma":[0.004454548,0.0002639732,0.0003746704,0.0009629388,0.0005443965,0.001049648,0.000355996,0.0001642928,0.9889613,0.001227225,0.001211419,0.0004295865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957877,0.001008406,0.002007621,0.0001692791,0.00009772272,0.00007674092,0.00006380457,0.00006242143,0.0007263219],"genre_scores_gemma":[0.9984903,0.0004251522,0.0006467724,0.0000542169,0.0002607417,0.000004251334,0.00002918644,0.00005768207,0.0000317328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01274917,"threshold_uncertainty_score":0.9999731,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01775449434246203,"score_gpt":0.2727735596988319,"score_spread":0.2550190653563699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}