{"id":"W2515540641","doi":"10.1039/c6cp04444a","title":"Photogenerated triplet states in supramolecular porphyrin ladder assemblies: an EPR study","year":2016,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Sleep & Circadian Network","funders":"European Research Council; Engineering and Physical Sciences Research Council; University of Oxford","keywords":"Porphyrin; Supramolecular chemistry; Electron paramagnetic resonance; Excited state; Photochemistry; Chemistry; Crystallography; Nuclear magnetic resonance; Physics; Crystal structure; Atomic physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000120629,0.0001450209,0.000138882,0.0001180839,0.0001380277,0.0001566685,0.000180758,0.0002155522,0.0009732675],"category_scores_gemma":[0.0001682482,0.00007642268,0.00008877616,0.00009655831,0.0002218185,0.0002806313,0.0001851721,0.0004789613,0.0001319853],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001385111,"about_ca_system_score_gemma":0.00007079653,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000243302,"about_ca_topic_score_gemma":0.000151147,"domain_scores_codex":[0.9999563,0.00000821934,0.00000196466,0.00001220532,0.00001045466,0.00001089536],"domain_scores_gemma":[0.9999202,0.00002515764,0.00001822757,0.000009291432,0.00001125116,0.00001581768],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004603723,0.00004115133,0.0001205448,0.00002235442,0.000002610185,0.00004163193,0.00003734881,0.0001293215,0.9985563,0.0001075434,0.00001769946,0.0008773603],"study_design_scores_gemma":[0.00002402108,0.0004727987,0.002030999,0.000005844454,0.00001051166,0.0001485281,0.00006309104,0.004379957,0.9922928,0.0001106921,0.0004546794,0.000006087509],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979571,0.0001857245,0.001444487,0.00002364235,0.000002831051,0.000005388964,0.00001676725,0.00001779871,0.0003461545],"genre_scores_gemma":[0.9985842,0.0001237876,0.000719548,0.00001213906,0.000002735145,0.000005900651,0.00003166798,0.000004517089,0.0005155739],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009732675,"threshold_uncertainty_score":0.003255844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01950065262837923,"score_gpt":0.2741792960915952,"score_spread":0.254678643463216,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}