{"id":"W2517068517","doi":"10.1021/acs.organomet.5b00585","title":"Modular <i>P</i>-Chirogenic Phosphine-Sulfide Ligands: Clear Evidence for Both Electronic Effect and <i>P</i>-Chirality Driving Enantioselectivity in Palladium-Catalyzed Allylations","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique; Université de Bourgogne","keywords":"Chemistry; Phosphinite; Substituent; Phosphine; Boranes; Palladium; Moiety; Medicinal chemistry; Catalysis; Allylic rearrangement; Chirality (physics); Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001600221,0.0004042451,0.0006243318,0.0002784336,0.0001841183,0.0001321701,0.000390096,0.0002376266,0.00008456867],"category_scores_gemma":[0.002413706,0.0003986851,0.0002443784,0.001493891,0.00009589615,0.0005208015,0.0001595621,0.0003756664,0.00002399587],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004474711,"about_ca_system_score_gemma":0.0003347131,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001279226,"about_ca_topic_score_gemma":0.0004494858,"domain_scores_codex":[0.9973511,0.00006683825,0.0005917178,0.0007902622,0.0004723953,0.0007276776],"domain_scores_gemma":[0.9979979,0.0006271703,0.0002678676,0.0006303504,0.0001427669,0.0003339324],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007299245,0.0008476384,0.1663526,0.0005979944,0.000998588,0.00002173932,0.001559138,0.001278966,0.8094853,0.002551437,0.0001934285,0.01538332],"study_design_scores_gemma":[0.008348763,0.0004605027,0.01671587,0.0002170658,0.000966758,0.0000646253,0.0002477108,0.02716667,0.9305049,0.003590993,0.009716537,0.001999611],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922818,0.003080354,0.003246428,0.0002357693,0.0000532493,0.0004082458,0.00002258962,0.0001566195,0.000514922],"genre_scores_gemma":[0.9981675,0.0005383054,0.000352063,0.0001113512,0.0001053039,0.0001175989,0.0001353697,0.00007701475,0.0003955438],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1496367,"threshold_uncertainty_score":0.9998465,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02553644237218825,"score_gpt":0.277721485123166,"score_spread":0.2521850427509778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}