{"id":"W2517434954","doi":"10.1149/2.f07024if","title":"Dissociative Electron Transfer","year":2002,"lang":"en","type":"article","venue":"The Electrochemical Society Interface","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Electron transfer; Marcus theory; Dissociative; Chemistry; Chemical reaction; Electron; Chemical physics; Nanotechnology; Materials science; Physics; Physical chemistry; Kinetics; Classical mechanics; Reaction rate constant; Nuclear physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009342824,0.0002733961,0.0002720472,0.000006861769,0.0002927055,0.00005319903,0.000636099,0.0001949734,0.002126068],"category_scores_gemma":[0.00003283207,0.0001906171,0.0005478599,0.0003693908,0.0001813013,0.00006074933,0.00005415428,0.0008988057,0.0002596934],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002464615,"about_ca_system_score_gemma":0.000009874766,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007542119,"about_ca_topic_score_gemma":0.00000231422,"domain_scores_codex":[0.9982527,0.00001788063,0.0003038461,0.0004170874,0.0003079637,0.0007005594],"domain_scores_gemma":[0.9991586,0.000212289,0.00005712483,0.0004007776,0.00005611912,0.0001150472],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009981335,0.0001466261,0.00002052971,0.00001121152,0.0002155798,8.884121e-8,0.0007592425,0.000001194501,0.9896616,0.0006714579,0.00811783,0.000384687],"study_design_scores_gemma":[0.0002184736,0.00002292182,0.000002361713,0.00001120086,0.0001061143,0.000005569384,0.0001352263,0.003110887,0.9756223,0.001442859,0.01907477,0.0002472945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9189258,0.004483699,0.03084336,0.0124333,0.00001856019,0.0002017099,0.00001681279,0.0005048856,0.03257189],"genre_scores_gemma":[0.9914768,0.0004457923,0.0001521842,0.0006041117,0.0002171806,0.00009547405,0.00002228483,0.00003365011,0.006952552],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07255098,"threshold_uncertainty_score":0.9987862,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008898550211170071,"score_gpt":0.2345904922265534,"score_spread":0.2256919420153833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}