{"id":"W2518031055","doi":"10.1021/acs.jpcc.5b06155","title":"In Situ X-ray Absorption Spectroscopic Study of Fe@Fe<sub><i>x</i></sub>O<sub><i>y</i></sub>/Pd and Fe@Fe<sub><i>x</i></sub>O<sub><i>y</i></sub>/Cu Nanoparticle Catalysts Prepared by Galvanic Exchange Reactions","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Nanomaterials for catalytic reactions","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of Saskatchewan","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; National Science Council; Deutscher Akademischer Austauschdienst","keywords":"XANES; Nanoparticle; Catalysis; Materials science; Scanning transmission electron microscopy; X-ray absorption spectroscopy; Transmission electron microscopy; Metal; Absorption (acoustics); In situ; Palladium; Absorption spectroscopy; Scanning electron microscope; Crystallography; Chemical engineering; Chemistry; Inorganic chemistry; Spectral line; Nanotechnology; Metallurgy; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001032823,0.0003404211,0.0001853378,0.0001924512,0.0001803132,0.0001778179,0.0002957081,0.0004644501,0.001465975],"category_scores_gemma":[0.0001300714,0.000286437,0.0001828599,0.0001628465,0.0002019266,0.0002603045,0.0001612735,0.0003770138,0.0002251425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002158663,"about_ca_system_score_gemma":0.00008363709,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007765123,"about_ca_topic_score_gemma":0.001176454,"domain_scores_codex":[0.9999168,0.00000686549,0.000006895372,0.00002717597,0.0000229362,0.0000193166],"domain_scores_gemma":[0.9999014,0.00002252673,0.0000295947,0.000009795514,0.00002542363,0.00001125799],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006290188,0.00001064758,0.0002255705,0.00003703723,0.000004957581,0.00007829228,0.00004130248,0.0001275761,0.9986234,0.00004698234,0.00006222166,0.000679181],"study_design_scores_gemma":[0.000005726329,0.00004859457,0.004012606,0.000004145001,0.00001108435,0.000124412,0.00004675666,0.001685773,0.9931861,0.00002210618,0.0008472184,0.000005470483],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948512,0.0004210129,0.002365524,0.00006098011,0.0000136521,0.000009662295,0.0002063352,0.00007709624,0.001994509],"genre_scores_gemma":[0.9950854,0.0002665829,0.002298986,0.00004143993,0.000005724447,0.00001520582,0.000253263,0.00002486909,0.002008501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001465975,"threshold_uncertainty_score":0.004904151,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01326536090899392,"score_gpt":0.2466410239171989,"score_spread":0.233375663008205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}