{"id":"W2518658550","doi":"10.1021/jacs.6b06943","title":"Borinic Acid Catalyzed Stereo- and Regioselective Couplings of Glycosyl Methanesulfonates","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":150,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Catalysis; Regioselectivity; Stereoselectivity; Glycosyl; Anomer; Diol; Glycosylation; Glycosyl donor; Stereochemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002119187,0.0004531304,0.000195014,0.0001735349,0.0001045405,0.0001899094,0.0002293923,0.0001827349,0.0007516164],"category_scores_gemma":[0.0001749297,0.0001276749,0.0001656322,0.0002080405,0.0001729257,0.0002329081,0.0002582577,0.0003067571,0.0002791923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002649086,"about_ca_system_score_gemma":0.0002502221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000377904,"about_ca_topic_score_gemma":0.0009218665,"domain_scores_codex":[0.9998447,0.00003782097,0.00001253931,0.000026848,0.00002793394,0.00005018389],"domain_scores_gemma":[0.9999365,0.00001055289,0.0000202513,0.00001026231,0.00000882425,0.00001365413],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001436868,0.00002848692,0.0002786033,0.00004546717,0.00001271005,0.00006040575,0.00003617568,0.0001819391,0.9949591,0.0008122992,0.00004567809,0.003395425],"study_design_scores_gemma":[0.00000599001,0.00006692074,0.0002788508,0.000001818922,0.00000547504,0.00003668129,0.000008822168,0.0002583961,0.9985361,0.00004056386,0.0007570905,0.000003254594],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898311,0.0007033678,0.006003612,0.00005534869,0.00003265679,0.00002858886,0.0001174726,0.00006653959,0.003161242],"genre_scores_gemma":[0.9953246,0.0004770785,0.002644629,0.00001865414,0.000006903796,0.00001090933,0.0001358027,0.00001639275,0.001364962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007516164,"threshold_uncertainty_score":0.002514422,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009733306785521038,"score_gpt":0.2327645343426894,"score_spread":0.2230312275571684,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}