{"id":"W2520195096","doi":"10.1139/cjc-2016-0134","title":"Solvation environment effects on the photoisomerization equilibrium of the model tannins catechin and epicatechin as natural sunscreens in aquatic systems","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saskatchewan Polytechnic","funders":"Western Canada Research Grid; Compute Canada","keywords":"Chemistry; Photoisomerization; Solvation; Catechin; Isomerization; Computational chemistry; Polarizable continuum model; Photochemistry; Solvophobic; Organic chemistry; Solvent; Polyphenol","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001955203,0.0002542783,0.0002370015,0.0001379298,0.0002752946,0.0002299698,0.0002486603,0.0002340175,0.00122147],"category_scores_gemma":[0.0003489185,0.0001386336,0.0003026431,0.0001483267,0.0002940968,0.0003625985,0.0003517971,0.000403631,0.0001330374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003651656,"about_ca_system_score_gemma":0.0002749497,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002458442,"about_ca_topic_score_gemma":0.001685096,"domain_scores_codex":[0.9999175,0.00001651832,0.000003411201,0.00001939965,0.00002016827,0.00002291191],"domain_scores_gemma":[0.999897,0.00006061362,0.00001267763,0.00000494342,0.00001735937,0.000007365675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005676533,0.0001238431,0.003469135,0.000464075,0.00006908732,0.0004146678,0.0004298231,0.08873139,0.8906805,0.006997874,0.0003928638,0.007659097],"study_design_scores_gemma":[0.00007934637,0.0008220192,0.006847254,0.00004155777,0.00007865301,0.0001431318,0.0003975774,0.4193228,0.5672588,0.00294457,0.001995537,0.00006875387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961631,0.0003142505,0.002387197,0.00006238788,0.000007143381,0.000008774242,0.0000764127,0.00002073268,0.000959955],"genre_scores_gemma":[0.9981771,0.0003518335,0.000939837,0.00001752519,0.00000192919,0.000015903,0.00009695675,0.000007077401,0.0003919746],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002458442,"threshold_uncertainty_score":0.004888296,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006225086974291103,"score_gpt":0.1758393477569517,"score_spread":0.1696142607826606,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}