{"id":"W2522389065","doi":"10.1002/anie.201607735","title":"Oxidative Cleavage of C=S and P=S Bonds at an Al<sup>I</sup> Center: Preparation of Terminally Bound Aluminum Sulfides","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Brock University","funders":"Ministerio de Economía y Competitividad; Government of Ontario; American Chemical Society","keywords":"Cleavage (geology); Center (category theory); Bond cleavage; Aluminium; Chemistry; Oxidative cleavage; Crystallography; Materials science; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001059022,0.0001494877,0.000194513,0.00006040731,0.00005490062,0.0000193592,0.000156612,0.0001261215,0.0009351959],"category_scores_gemma":[0.0001639803,0.0001166318,0.00008270328,0.0000458382,0.000217815,0.0004499434,0.00008065449,0.00006860741,0.000005811503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001365336,"about_ca_system_score_gemma":0.00002452629,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004422179,"about_ca_topic_score_gemma":0.00002133647,"domain_scores_codex":[0.9988307,0.00001117232,0.0003911517,0.0002948773,0.000337138,0.0001349139],"domain_scores_gemma":[0.9990105,0.0001921441,0.0003119989,0.000192624,0.0002095818,0.00008315688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001877898,0.0002365959,0.002000222,0.00004413679,0.00008196927,0.000001715877,0.000275207,7.696399e-7,0.9868593,0.00009993973,0.007630158,0.002582217],"study_design_scores_gemma":[0.0006156928,0.0000496901,0.0006238264,0.0002084029,0.00003197855,0.0000257424,0.0001707129,0.00008788407,0.9812157,0.0004302118,0.01640626,0.0001338578],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835543,0.00005494688,0.0001581754,0.0005565188,0.00008083726,0.00005423586,0.0005817768,0.0000299868,0.01492924],"genre_scores_gemma":[0.9973194,0.0002374193,0.0001416216,0.00004386388,0.0004014426,0.0000228095,0.0004790096,0.00001635373,0.001338056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01376514,"threshold_uncertainty_score":0.9999781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01414134556621927,"score_gpt":0.2751170310927434,"score_spread":0.2609756855265242,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}