{"id":"W2522960562","doi":"10.1039/c6dt02416e","title":"Increasing the triplet lifetime and extending the ground-state absorption of biscyclometalated Ir(<scp>iii</scp>) complexes for reverse saturable absorption and photodynamic therapy applications","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":107,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Canadian Institutes of Health Research; National Science Foundation","keywords":"Chemistry; Excited state; Diimine; Photochemistry; Absorption (acoustics); Ligand (biochemistry); Singlet state; Triplet state; Ultrafast laser spectroscopy; Saturable absorption; Absorption spectroscopy; Ground state; Materials science; Molecule; Laser; Atomic physics; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006331478,0.0001764421,0.000199635,0.0001566274,0.0004362939,0.00007909544,0.0001620884,0.0000805548,0.00001869214],"category_scores_gemma":[0.00003624825,0.000105105,0.00007394361,0.0003763894,0.0002683978,0.0002611839,0.000008183735,0.0001903894,0.000005801383],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008069304,"about_ca_system_score_gemma":0.00002052902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002100962,"about_ca_topic_score_gemma":0.00005172514,"domain_scores_codex":[0.9988819,0.00009904246,0.0003176727,0.0002326672,0.0001791589,0.0002895518],"domain_scores_gemma":[0.9982288,0.001244858,0.00008385224,0.0003022987,0.00007108393,0.00006913254],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003219689,0.0000342953,0.00008551028,0.00008440503,0.000147557,1.662995e-7,0.00077278,0.0002001743,0.9860152,0.0002383985,0.00006556058,0.01232377],"study_design_scores_gemma":[0.008029308,0.0003489581,0.02859827,0.0004207127,0.0004359272,0.0002571837,0.002531651,0.08444811,0.8025329,0.002355137,0.06936985,0.0006719981],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8725933,0.0009791172,0.1245386,0.0003018439,0.00008275869,0.001111544,0.0001793264,0.0001503918,0.00006308153],"genre_scores_gemma":[0.9941421,0.004662658,0.000505415,0.0000185248,0.00004372788,0.000259343,0.00002173895,0.00004850105,0.0002979928],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1834823,"threshold_uncertainty_score":0.4286057,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01231850391321754,"score_gpt":0.2419094981189332,"score_spread":0.2295909942057157,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}