{"id":"W2523019448","doi":"10.1016/j.chroma.2016.09.045","title":"System maps for retention of small neutral compounds on a superficially porous particle column in reversed-phase liquid chromatography","year":2016,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":false,"ca_institutions":"CanAm Bioresearch (Canada)","funders":"","keywords":"Chemistry; Chromatography; Reversed-phase chromatography; Chromatography column; Porosity; Phase (matter); Column (typography); Hydrophilic interaction chromatography; Countercurrent chromatography; High-performance liquid chromatography; Particle (ecology); Column chromatography; Stationary phase; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006795414,0.0004107201,0.001022225,0.0005063502,0.0001098938,0.00004780445,0.0005469539,0.0003406348,0.00004618114],"category_scores_gemma":[0.00008716427,0.0003218343,0.001420121,0.0009598086,0.000240459,0.0002546522,0.00003921609,0.0003020327,0.000003400142],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001044214,"about_ca_system_score_gemma":0.0001461614,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001894918,"about_ca_topic_score_gemma":0.00001923926,"domain_scores_codex":[0.996538,0.00008022261,0.001824231,0.0004073456,0.000521557,0.0006285711],"domain_scores_gemma":[0.9973562,0.0002602622,0.001140088,0.0004933284,0.0004045416,0.0003455619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005738325,0.002320176,0.01693457,0.00223326,0.0007233709,0.0002462759,0.0001830914,0.00001594392,0.9654938,0.004215054,0.001515713,0.0003804553],"study_design_scores_gemma":[0.01731693,0.003499095,0.001484061,0.005439178,0.0005427451,0.000567243,0.002180272,0.0001390747,0.9657829,0.0009261459,0.001345533,0.0007768677],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969011,0.00030385,0.0004843648,0.0002494489,0.0001677098,0.0002065059,0.0001957915,0.0000723409,0.001418875],"genre_scores_gemma":[0.9988744,0.00008052221,0.0006220802,0.00003748107,0.0002585829,0.00002897046,0.00001490934,0.00005279759,0.00003024978],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01545051,"threshold_uncertainty_score":0.9999233,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01847466873150246,"score_gpt":0.2474181462875272,"score_spread":0.2289434775560248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}