{"id":"W2523844273","doi":"10.1021/acs.jpcc.6b08127","title":"Spatial Mapping of Methanol Oxidation Activity on a Monolithic Variable-Composition PtNi Alloy Using Synchrotron Infrared Microspectroscopy","year":2016,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saskatchewan Research Council (Canada); Canadian Light Source (Canada); University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Light Source","keywords":"Alloy; Synchrotron; Methanol; Electrocatalyst; Electrochemistry; Infrared; Materials science; Metal; Analytical Chemistry (journal); Synchrotron radiation; Reaction rate; Electrode; Diffraction; Chemical engineering; Chemistry; Metallurgy; Physical chemistry; Catalysis; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009443046,0.0001847812,0.0001843163,0.0002546403,0.0001569794,0.0002541249,0.0002913184,0.0002559386,0.0005199074],"category_scores_gemma":[0.0001434608,0.0001783541,0.000127255,0.0001648311,0.0001876369,0.0001589267,0.000127691,0.0002249123,0.0001466812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003011112,"about_ca_system_score_gemma":0.0001166063,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009155723,"about_ca_topic_score_gemma":0.001536328,"domain_scores_codex":[0.9999276,0.00000460792,0.000003409011,0.00002405719,0.00002823493,0.00001193667],"domain_scores_gemma":[0.9999223,0.00001949691,0.00002037631,0.000009492707,0.00001824212,0.00001007316],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001528747,0.000003292998,0.00009273228,0.00000571353,9.012211e-7,0.000009667902,0.000006694551,0.00006349124,0.9993674,0.0000201704,0.000006611599,0.0004080501],"study_design_scores_gemma":[0.000003623107,0.00004635352,0.003764234,0.000001904591,0.000005280726,0.00004818023,0.0000126595,0.003865436,0.9919838,0.00001413234,0.0002512735,0.000002935842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943542,0.0002118068,0.004498213,0.00002611949,0.000005841847,0.000006370457,0.000123366,0.0001021324,0.0006718849],"genre_scores_gemma":[0.9886435,0.0001922431,0.009947382,0.00001422675,0.000004673435,0.00001293276,0.0001085321,0.00001766663,0.001058765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009155723,"threshold_uncertainty_score":0.002184689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106138404757071,"score_gpt":0.2384237161799065,"score_spread":0.2278098757041994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}