{"id":"W2529552724","doi":"10.1021/acs.inorgchem.6b01594","title":"Ultrafast Singlet Energy Transfer in Porphyrin Dyads","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds de recherche du Québec – Nature et technologies; Centre National de la Recherche Scientifique; Université de Strasbourg; Agence Nationale de la Recherche","keywords":"Chemistry; Porphyrin; Chromophore; Photochemistry; Singlet state; Acceptor; Energy transfer; Ultrashort pulse; Linker; Zinc; Fluorescence; Förster resonance energy transfer; Free base; Chemical physics; Excited state; Physical chemistry; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007403937,0.0001867623,0.0001640509,0.0001006069,0.0001864048,0.0002263338,0.0001251942,0.0001523375,0.001066805],"category_scores_gemma":[0.0001237561,0.00008256178,0.00006443938,0.00009410245,0.0001323649,0.0001873421,0.0001716782,0.0003004851,0.0002026762],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004479094,"about_ca_system_score_gemma":0.0001530136,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004779404,"about_ca_topic_score_gemma":0.0005363996,"domain_scores_codex":[0.999951,0.000009134395,0.000002126217,0.00001191191,0.000009513279,0.00001626917],"domain_scores_gemma":[0.9999576,0.00001141919,0.000006943489,0.000003348373,0.000004941136,0.00001586075],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001074316,0.0000277225,0.0001317125,0.00003492278,0.000002480025,0.00005809536,0.00003589577,0.0002985018,0.9966117,0.0004553172,0.0000648792,0.002171384],"study_design_scores_gemma":[0.00001673594,0.0001776772,0.0006187574,0.000002267127,0.000005513463,0.00006476297,0.00001552243,0.001492031,0.9964517,0.00006211406,0.001089112,0.000003824334],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997409,0.0001759515,0.001476793,0.00003432565,0.000005823138,0.000005354288,0.00002672667,0.00004399274,0.0008219486],"genre_scores_gemma":[0.9976454,0.00009004022,0.0006364657,0.00001255824,0.000001422389,0.000007977254,0.00003173052,0.000009615434,0.001564754],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001066805,"threshold_uncertainty_score":0.003568828,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006787051600222156,"score_gpt":0.1907327023449571,"score_spread":0.1839456507447349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}