{"id":"W2529958684","doi":"10.1002/anie.201608169","title":"Strong Evidence of a Phosphanoxyl Complex: Formation, Bonding, and Reactivity of Ligated Phosphorus Analogues of Nitroxides","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Reactivity (psychology); Phosphorus; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001090371,0.0002156725,0.0001253743,0.0001193179,0.0001590006,0.0002587262,0.0003250036,0.0003195093,0.003832582],"category_scores_gemma":[0.0002422635,0.0001294183,0.00005777697,0.00008440457,0.0003165971,0.0002401553,0.0003214847,0.0003364586,0.0002371765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001350337,"about_ca_system_score_gemma":0.00008675706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001936355,"about_ca_topic_score_gemma":0.000305811,"domain_scores_codex":[0.999921,0.000009294567,0.000003089233,0.00001921978,0.0000251979,0.00002220897],"domain_scores_gemma":[0.9998956,0.00003547079,0.00002821739,0.00001577722,0.00001026347,0.00001470725],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002050635,0.00003078345,0.00045199,0.00009572311,0.000009898209,0.0001505453,0.000118499,0.0002362811,0.995682,0.001543638,0.0001467854,0.001328849],"study_design_scores_gemma":[0.0000225027,0.0002002745,0.001404696,0.000007226301,0.00001065165,0.0001116282,0.00006091593,0.001342635,0.9955664,0.0002495983,0.001018116,0.000005198768],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954121,0.000177833,0.001293582,0.00005677557,0.000004816139,0.000006714338,0.00006715961,0.00002957065,0.002951497],"genre_scores_gemma":[0.9991431,0.0000586378,0.0002233308,0.000008542582,0.000001327291,0.000004817913,0.00004683148,0.000005899007,0.0005075545],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003832582,"threshold_uncertainty_score":0.01282126,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03573785503175683,"score_gpt":0.2914606583354824,"score_spread":0.2557228033037256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}