{"id":"W2530705235","doi":"10.1002/chem.201603398","title":"“Shine & Click” Photo‐Induced Interfacial Unmasking of Strained Alkynes on Small Water‐Soluble Gold Nanoparticles","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Alkyne; Cycloaddition; Click chemistry; Colloidal gold; Chemistry; Azide; Ligand (biochemistry); Photochemistry; Surface modification; Nanoparticle; Combinatorial chemistry; Nanotechnology; Organic chemistry; Materials science; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005014004,0.0003825562,0.0003570671,0.00002912658,0.0002153698,0.0001096654,0.0008062241,0.0001075324,0.004303067],"category_scores_gemma":[0.0002445727,0.0002627842,0.0002580973,0.0001037347,0.000185188,0.0001072603,0.0002029992,0.0005248509,0.0001718705],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001070131,"about_ca_system_score_gemma":0.0000605999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003110252,"about_ca_topic_score_gemma":0.00000143326,"domain_scores_codex":[0.9976938,0.00005241083,0.0008823167,0.0004758359,0.0003072247,0.0005884264],"domain_scores_gemma":[0.998233,0.0001192441,0.0004201048,0.0006912856,0.0001638876,0.0003724667],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001611995,0.0002528642,0.0001299289,0.0001295074,0.00007791648,0.00005190429,0.0002996378,0.000006124807,0.9913114,0.00001156821,0.00101198,0.006555925],"study_design_scores_gemma":[0.001631425,0.00003151176,0.00003881825,0.0004849432,0.00004655268,0.0002907139,0.0001490825,0.00001342353,0.9729245,0.0001250091,0.02390411,0.0003599317],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9685185,0.00002987865,0.0001187618,0.0005854882,0.00008543742,0.00004569507,0.00004893741,0.000105668,0.03046164],"genre_scores_gemma":[0.988022,0.00003510783,0.0001817278,0.00005185159,0.0009132997,0.00000805408,0.00003224139,0.0000771532,0.01067852],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02289213,"threshold_uncertainty_score":0.9999824,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04836134896778754,"score_gpt":0.2534296177658112,"score_spread":0.2050682687980236,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}