{"id":"W2530957428","doi":"10.1039/c6cc07626b","title":"Dehydrative condensation of carbonyls with non-acidic methylenes enabled by light: synthesis of benzofurans","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Chemistry; Condensation; Organic chemistry; Polymer chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001101992,0.000203223,0.000435765,0.00005248274,0.00007324185,0.000007671746,0.0009499579,0.0002095948,0.0002334825],"category_scores_gemma":[0.0009712483,0.0001419681,0.0001322576,0.0002878967,0.001107728,0.0001283026,0.0001591639,0.0002368975,0.000008338789],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001360472,"about_ca_system_score_gemma":0.0001032864,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001424759,"about_ca_topic_score_gemma":0.00001545127,"domain_scores_codex":[0.9986051,0.00004788186,0.000565308,0.0002618975,0.0002977658,0.0002220668],"domain_scores_gemma":[0.995169,0.002329108,0.0003657246,0.001697862,0.0002830576,0.0001552914],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004722518,0.0002693189,0.0002329407,0.00006244487,0.0001271513,1.6629e-7,0.000167673,3.525919e-7,0.9973737,0.0005434204,0.0003197818,0.0008558396],"study_design_scores_gemma":[0.0004611666,0.00001732639,0.00002237147,0.0002956153,0.000137123,0.000002626916,0.0002207781,0.00005844132,0.9964207,0.0008421179,0.001338445,0.0001832967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9471859,0.0004291121,0.0007833589,0.004136975,0.00001129195,0.0002392149,0.0003089181,0.00009043792,0.04681476],"genre_scores_gemma":[0.9970994,0.0001702743,0.002128954,0.00001964655,0.00001408168,0.0002421965,0.00004891325,0.00003180555,0.0002447294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04991347,"threshold_uncertainty_score":0.5789289,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01227303269488103,"score_gpt":0.2473082572362282,"score_spread":0.2350352245413472,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}