{"id":"W2531985189","doi":"10.1021/acscatal.6b01719","title":"Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate","year":2016,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":341,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Connaught Fund; Natural Sciences and Engineering Research Council of Canada; Canadian Institute for Advanced Research","keywords":"Overpotential; Catalysis; Formate; Rational design; Formic acid; Electrosynthesis; Palladium; Faraday efficiency; Electrochemistry; Chemistry; Electrocatalyst; Electrochemical reduction of carbon dioxide; Selectivity; Inorganic chemistry; Materials science; Chemical engineering; Nanotechnology; Organic chemistry; Physical chemistry; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003762076,0.0005373939,0.0005213803,0.0003121301,0.0002165711,0.0008899791,0.0005922703,0.0003632133,0.0005312992],"category_scores_gemma":[0.0005374641,0.0004562396,0.0002585255,0.0002212123,0.0003843723,0.0004242233,0.0003085719,0.0006063655,0.0003141377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007364447,"about_ca_system_score_gemma":0.0005318284,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005907591,"about_ca_topic_score_gemma":0.002077099,"domain_scores_codex":[0.9998281,0.00002322085,0.00001560652,0.00003008516,0.00007173989,0.00003123205],"domain_scores_gemma":[0.9999372,0.00001810958,0.00001286827,0.000006868105,0.00001580143,0.000009171243],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004049084,0.000425543,0.001134347,0.0006201169,0.00008838339,0.0005611128,0.0001330103,0.09018642,0.861401,0.01305022,0.000880706,0.03111414],"study_design_scores_gemma":[0.0001752304,0.000669508,0.0007051097,0.00002084737,0.00005419021,0.0001477982,0.00009930719,0.193565,0.791137,0.002010173,0.01137631,0.00003954743],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9022865,0.002594269,0.08240682,0.0005127013,0.0001066266,0.00039633,0.0002891728,0.0004128052,0.01099491],"genre_scores_gemma":[0.9523348,0.001628689,0.04367006,0.00006277762,0.000009227258,0.0001263271,0.0001826749,0.00005703579,0.001928491],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008899791,"threshold_uncertainty_score":0.005343318,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01288669217439411,"score_gpt":0.241162999483433,"score_spread":0.2282763073090389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}