{"id":"W2533447106","doi":"10.1021/acs.jpcc.6b09202","title":"Role of Au(I) Intermediates in the Electrochemical Formation of Highly Anisotropic Gold Nanostructures with Near-IR SERS Applications","year":2016,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Raman spectroscopy; Plasmon; Electrochemistry; Nanostructure; Electron transfer; Disproportionation; Chemistry; Materials science; Photochemistry; Chemical physics; Electrode; Nanotechnology; Physical chemistry; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003561852,0.0006117474,0.0002965864,0.0002436548,0.0001529104,0.0005373189,0.0006346218,0.0005715657,0.0005463458],"category_scores_gemma":[0.0006451249,0.0003710356,0.0002906991,0.0001478469,0.0002794812,0.0004074412,0.0004169927,0.0006172127,0.0003365926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002525912,"about_ca_system_score_gemma":0.0001445282,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003066521,"about_ca_topic_score_gemma":0.0003839062,"domain_scores_codex":[0.9997088,0.00005462061,0.00002203995,0.00006458674,0.0001058175,0.00004407942],"domain_scores_gemma":[0.9998272,0.00005427045,0.00004448161,0.00001786168,0.00003070808,0.00002545279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001698555,0.000009110955,0.00007586662,0.00004097923,0.000003478912,0.00005999667,0.00003371265,0.00009724063,0.9980645,0.0001541799,0.00001536869,0.001428625],"study_design_scores_gemma":[0.000003999041,0.00006504733,0.0003038552,0.000003257845,0.000004860564,0.00009128487,0.0000125879,0.001132107,0.9978973,0.00006011054,0.0004217153,0.000003833558],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9634394,0.004081352,0.02639551,0.0002308606,0.00006752086,0.0001056937,0.00008845772,0.0004016838,0.005189576],"genre_scores_gemma":[0.9810034,0.0009516519,0.0164325,0.00005205927,0.00001267407,0.00002471152,0.00005224732,0.00002487708,0.001445852],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006346218,"threshold_uncertainty_score":0.001883686,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003658346673887147,"score_gpt":0.2014592176953889,"score_spread":0.1978008710215017,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}