{"id":"W2543057000","doi":"10.1039/c6ob02191c","title":"Photochemical formation of quinone methides from peptides containing modified tyrosine","year":2016,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Social Fund; Hrvatska Zaklada za Znanost; Royal Society; Royal Society of Chemistry; University of Victoria","keywords":"Chemistry; Quinone methide; Quinone; Peptide; Tyrosine; Combinatorial chemistry; Photochemistry; Stereochemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001791321,0.0002136572,0.00008530395,0.00007189193,0.00009926407,0.000106403,0.0001337751,0.0001831487,0.001385827],"category_scores_gemma":[0.0002629478,0.0000771723,0.0001036464,0.00006802251,0.0001403774,0.0001855984,0.0001204355,0.0003077824,0.0002105989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001677466,"about_ca_system_score_gemma":0.00009599781,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003824658,"about_ca_topic_score_gemma":0.0005013816,"domain_scores_codex":[0.9999416,0.000008916792,0.000001975399,0.00001814348,0.00001254556,0.00001675698],"domain_scores_gemma":[0.9998486,0.00004519112,0.00004522273,0.00001615709,0.00002213458,0.00002265925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005043657,0.000006805087,0.0001077892,0.00003184774,0.000002744888,0.0000394702,0.0000326858,0.00005369186,0.9982178,0.0001090692,0.00002110146,0.00132655],"study_design_scores_gemma":[0.000004209612,0.0001315203,0.001059241,0.000002370928,0.000002653288,0.00006326406,0.00001038545,0.0002520776,0.9977182,0.00002893684,0.0007248661,0.000002322892],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937623,0.000743585,0.003494177,0.00002898731,0.00001204793,0.00002202428,0.00009928404,0.00002581745,0.001811771],"genre_scores_gemma":[0.9971614,0.0002287406,0.001297529,0.00001217821,0.000003070594,0.00000912484,0.00007057976,0.00001005273,0.001207395],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001385827,"threshold_uncertainty_score":0.004636109,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0137399101656454,"score_gpt":0.229901552749664,"score_spread":0.2161616425840185,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}