{"id":"W2543057000","doi":"10.1039/c6ob02191c","title":"Photochemical formation of quinone methides from peptides containing modified tyrosine","year":2016,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Social Fund; Hrvatska Zaklada za Znanost; Royal Society; Royal Society of Chemistry; University of Victoria","keywords":"Chemistry; Quinone methide; Quinone; Peptide; Tyrosine; Combinatorial chemistry; Photochemistry; Stereochemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001436998,0.0003253947,0.000438075,0.00003223219,0.00005903176,0.00002950808,0.0004964824,0.0003221868,0.003474151],"category_scores_gemma":[0.001007968,0.0002680567,0.0001803049,0.0001539816,0.000256902,0.0001865349,0.0001693262,0.0001470575,0.00004873296],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000154014,"about_ca_system_score_gemma":0.00008122923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003598907,"about_ca_topic_score_gemma":0.000001069321,"domain_scores_codex":[0.9981546,0.00002465367,0.0005913228,0.000468262,0.0004077781,0.0003533728],"domain_scores_gemma":[0.9982821,0.0003102302,0.0003935836,0.000709917,0.0001682256,0.0001359762],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001155699,0.00008708142,0.0001803994,0.00017186,0.0001114308,0.0000148529,0.000241752,5.397993e-8,0.9976322,0.000007484785,0.0001290991,0.001308215],"study_design_scores_gemma":[0.001145482,0.00001187418,0.00003137164,0.0005077836,0.0000608297,0.0000208132,0.0005672118,0.00004196347,0.9967893,0.0002714897,0.0002072398,0.0003446813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9453805,0.0004412805,0.04826277,0.0003028397,0.00002591024,0.0000748079,0.0001207944,0.0001548991,0.005236196],"genre_scores_gemma":[0.997711,0.00004344805,0.001606655,0.00005558775,0.000158701,0.00002611019,0.00009788251,0.00006374731,0.0002368764],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05233049,"threshold_uncertainty_score":0.9999772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0137399101656454,"score_gpt":0.229901552749664,"score_spread":0.2161616425840185,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}