{"id":"W2543172877","doi":"10.1021/acs.nanolett.6b03958","title":"Conformational Contrast of Surface-Mediated Molecular Switches Yields Ångstrom-Scale Spatial Resolution in Ultrahigh Vacuum Tip-Enhanced Raman Spectroscopy","year":2016,"lang":"en","type":"article","venue":"Nano Letters","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":119,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Air Force Office of Scientific Research; Basic Energy Sciences; Division of Materials Research; Division of Chemistry; Natural Sciences and Engineering Research Council of Canada","keywords":"Raman spectroscopy; Porphyrin; Molecule; Spectroscopy; Chemistry; Chemical physics; Resolution (logic); Surface-enhanced Raman spectroscopy; Metastability; Ultra-high vacuum; Analytical Chemistry (journal); Adsorption; Scanning tunneling microscope; Materials science; Raman scattering; Nanotechnology; Photochemistry; Physical chemistry; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001581508,0.0001778521,0.0001912986,0.0001390994,0.0001120718,0.0004456963,0.0003752901,0.0002186528,0.001200292],"category_scores_gemma":[0.0004015471,0.0002385592,0.0001494879,0.0001095665,0.0004175641,0.0003531351,0.0003680654,0.0005756966,0.0002051361],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002339796,"about_ca_system_score_gemma":0.00009347765,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002209309,"about_ca_topic_score_gemma":0.0002969744,"domain_scores_codex":[0.999826,0.00002644806,0.000007383289,0.00004303541,0.00005767628,0.00003940149],"domain_scores_gemma":[0.9998205,0.00008388508,0.00003371462,0.0000278537,0.00001839187,0.00001570677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002376765,0.000005490112,0.0001562056,0.00001412852,0.000002019231,0.00001953383,0.00002266686,0.0001187909,0.9980339,0.000243729,0.00002253641,0.001337179],"study_design_scores_gemma":[0.000003902734,0.00004276876,0.001089675,0.000001494035,0.000002994959,0.00006719866,0.00002516657,0.003382817,0.9949436,0.0001284212,0.0003066197,0.000005312012],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902143,0.0002028895,0.008490037,0.00004847833,0.00001292662,0.000004946427,0.00004036738,0.0001265148,0.0008594999],"genre_scores_gemma":[0.9958192,0.0001091666,0.003560598,0.0000178892,0.000004028235,0.000005885143,0.00002696148,0.00001410288,0.000442127],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001200292,"threshold_uncertainty_score":0.004015386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006214959978313338,"score_gpt":0.2068314929491294,"score_spread":0.200616532970816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}