{"id":"W2543804341","doi":"10.1139/cjc-2016-0488","title":"π-Extended fluoranthene imide derivatives: synthesis, structures, and electronic and optical properties","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science","keywords":"Fluoranthene; Imide; Chemistry; Bathochromic shift; Excited state; Intramolecular force; Photochemistry; Molecule; Density functional theory; Crystallography; Computational chemistry; Stereochemistry; Organic chemistry; Atomic physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002432998,0.0001280931,0.0002296104,0.00003510211,0.00009015192,0.0001084613,0.0001642696,0.00007574332,0.0004612342],"category_scores_gemma":[0.0003897391,0.00007604534,0.00002557734,0.00002513963,0.0004053914,0.0002112652,0.00001813557,0.00007071902,0.00000322315],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007795964,"about_ca_system_score_gemma":0.0006547296,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001231096,"about_ca_topic_score_gemma":0.0001296866,"domain_scores_codex":[0.9990901,0.00002617058,0.0002606973,0.0001478746,0.0001173519,0.0003578207],"domain_scores_gemma":[0.9992172,0.00004669749,0.0001222485,0.0001142286,0.00008999237,0.0004096559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004175026,0.00000343635,0.00054718,0.00005575089,0.00001088392,0.00003397074,0.0001157952,8.345943e-8,0.9975991,0.00007464547,0.0001353834,0.001381999],"study_design_scores_gemma":[0.0002431355,0.00002551789,0.002453342,0.0002092797,0.00001825219,0.0004498652,0.0001133997,5.240959e-7,0.9950036,0.000709547,0.0006520734,0.0001214906],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970856,0.001836004,0.00002284628,0.0008079913,0.00007819835,0.00003957177,0.00001526756,0.000005351948,0.0001091719],"genre_scores_gemma":[0.9993078,0.0002211888,0.0001669997,0.00004136113,0.0001713206,0.00000197251,2.120091e-7,0.00001154655,0.00007767259],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002595549,"threshold_uncertainty_score":0.5050191,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009126867839025195,"score_gpt":0.1962336103818497,"score_spread":0.1871067425428245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}