{"id":"W2546562504","doi":"10.1021/acs.inorgchem.6b01936","title":"Preparation, X-ray Structures, Spectroscopic, and Redox Properties of Di- and Trinuclear Iron–Zirconium and Iron–Hafnium Porphyrinoclathrochelates","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Division of Chemistry; Ministry of Education and Science of the Russian Federation; Russian Foundation for Basic Research; University of Manitoba","keywords":"Chemistry; Transmetalation; Redox; Porphyrin; Density functional theory; Electrospray ionization; Crystallography; Electrochemistry; Zirconium; Tetraphenylporphyrin; Inorganic chemistry; Mass spectrometry; Photochemistry; Physical chemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001360219,0.0002404571,0.0001565274,0.0001727598,0.0001277487,0.0001481666,0.0002889575,0.0001730124,0.0005255415],"category_scores_gemma":[0.000199636,0.000140957,0.00008216146,0.0001802609,0.0001325418,0.0001271321,0.0001832154,0.0002265869,0.0001371251],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003058413,"about_ca_system_score_gemma":0.0001142705,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009605638,"about_ca_topic_score_gemma":0.001051417,"domain_scores_codex":[0.9999309,0.00001002633,0.000006450354,0.00001794772,0.00001926986,0.00001543897],"domain_scores_gemma":[0.9999229,0.00001094941,0.00001921663,0.00001263613,0.00001437946,0.00001992303],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001032632,0.000007491218,0.0001837697,0.00003627517,0.00000502187,0.00003387883,0.00002735643,0.0001371437,0.9979628,0.00008203765,0.00002878971,0.001392083],"study_design_scores_gemma":[0.00001679533,0.0001604054,0.002395941,0.000003413364,0.00001074221,0.0001530015,0.0000224641,0.0007083307,0.9948068,0.00002579007,0.001689769,0.000006435956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968019,0.0003655874,0.001970548,0.00002039425,0.000002822794,0.00001813141,0.0002356723,0.000028594,0.0005564625],"genre_scores_gemma":[0.9933404,0.000342202,0.004336769,0.00001366485,0.000002590249,0.00002657732,0.000574494,0.00001598859,0.001347204],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009605638,"threshold_uncertainty_score":0.002219081,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006884759245238877,"score_gpt":0.2128583026906258,"score_spread":0.2059735434453869,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}