{"id":"W2547210996","doi":"10.1021/acs.organomet.6b00711","title":"Iron(II) Complexes Containing Chiral Unsymmetrical PNP′ Pincer Ligands: Synthesis and Application in Asymmetric Hydrogenations","year":2016,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Technische Universität Wien; University of Toronto; Austrian Science Fund","keywords":"Chemistry; Pincer movement; Ferrocene; Anhydrous; Yield (engineering); Catalysis; Hydride; Medicinal chemistry; Stereochemistry; Organic chemistry; Hydrogen; Electrochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726451,0.0003802634,0.0003691301,0.000256237,0.0001555542,0.0004193955,0.000521339,0.0003946461,0.0007382839],"category_scores_gemma":[0.0002776739,0.0002317991,0.00011717,0.0001904834,0.0002757943,0.0002909362,0.0003561056,0.0003191382,0.0002903678],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004155774,"about_ca_system_score_gemma":0.0001419354,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004472127,"about_ca_topic_score_gemma":0.0006934353,"domain_scores_codex":[0.9998474,0.00002429221,0.000009628333,0.00002400695,0.00004807688,0.00004655969],"domain_scores_gemma":[0.9999187,0.00001070127,0.00001634165,0.00001150749,0.00001551968,0.00002724137],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002589229,0.00005141928,0.0001836504,0.0001507882,0.00001189828,0.0002629494,0.00004062056,0.0005361447,0.9896064,0.0004532947,0.0001448728,0.008298933],"study_design_scores_gemma":[0.00003081455,0.0001230124,0.0002505331,0.00000461026,0.00001049751,0.0001894994,0.00001094156,0.0006789367,0.9963962,0.00004766229,0.002250624,0.000006791367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9791972,0.003043361,0.01045617,0.0001700691,0.00004423126,0.0000889646,0.0002242234,0.0002135979,0.006562126],"genre_scores_gemma":[0.9916086,0.001051195,0.00527878,0.00004921361,0.00001055217,0.00002370844,0.0001498365,0.00002131755,0.001806832],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007382839,"threshold_uncertainty_score":0.00301522,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01014903204602836,"score_gpt":0.2312260065910854,"score_spread":0.221076974545057,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}