{"id":"W2547356025","doi":"10.1039/c6sc04371b","title":"A palladium-catalyzed synthesis of (hetero)aryl-substituted imidazoles from aryl halides, imines and carbon monoxide","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Aryl; Palladium; Carbon monoxide; Halide; Catalysis; Chemistry; Monoxide; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002935984,0.0001841356,0.0002806085,0.00006965655,0.00006349946,0.00003688522,0.0004564511,0.0001115801,0.0003693784],"category_scores_gemma":[0.002615989,0.0001345884,0.00006290996,0.000355838,0.001238913,0.0001929591,0.0002296302,0.00006820506,0.000006335072],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001239531,"about_ca_system_score_gemma":0.0001265916,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002925858,"about_ca_topic_score_gemma":0.00000771401,"domain_scores_codex":[0.9982799,0.000006752885,0.0003638882,0.0005878286,0.0004700511,0.0002916164],"domain_scores_gemma":[0.9980847,0.0009044535,0.0001650457,0.0004865063,0.0001330311,0.0002262804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003873538,0.0000313231,0.007340088,0.00003064023,0.00001446852,0.000001839568,0.00004414318,0.000001621467,0.9882798,0.0001007411,0.00002145437,0.004095117],"study_design_scores_gemma":[0.0003194698,9.932468e-7,0.002377975,0.0001472759,0.00003855788,0.00001005598,0.00002438084,0.0004751774,0.9954938,0.0008244276,0.00009540381,0.0001924416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978678,0.0001645099,0.0004760044,0.0002928191,0.00008372476,0.00004609376,0.00007565368,0.00006786883,0.0009254829],"genre_scores_gemma":[0.9971481,0.00004268239,0.002601515,0.00001437299,0.000103391,0.00002108886,0.0000145865,0.00001372915,0.00004051128],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007214013,"threshold_uncertainty_score":0.5488357,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01818583555717659,"score_gpt":0.253863408386897,"score_spread":0.2356775728297204,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}