{"id":"W2547560523","doi":"","title":"Extending and diverting the photochemical nucleophile-olefin combination, aromatic substitution (photo-NOCAS) reaction.","year":2001,"lang":"en","type":"article","venue":"Library and Archives Canada (Government of Canada)","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Allene; Regioselectivity; Nucleophile; Photochemistry; Cycloaddition; Olefin fiber; Intramolecular force; Substitution reaction; Medicinal chemistry; Nucleophilic substitution; Methanol; Reaction mechanism; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00001165915,0.0001559932,0.0001500766,0.00001125024,0.0003854702,0.00003332667,0.0001418009,0.00003626908,0.0002456074],"category_scores_gemma":[0.00001976417,0.0001412913,0.00002323909,0.00008155888,0.0001220276,0.0002790582,0.00009355595,0.0001914887,7.888741e-9],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002296117,"about_ca_system_score_gemma":0.0003140572,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001043781,"about_ca_topic_score_gemma":0.001267503,"domain_scores_codex":[0.9984981,0.0000163922,0.0002755408,0.0002235402,0.0007819307,0.000204503],"domain_scores_gemma":[0.9991568,0.0003040147,0.0001804009,0.0001999771,8.430512e-7,0.0001579743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007490251,0.0000393614,0.009622809,0.0001052607,0.00004873835,0.00003399129,0.00005183521,0.000003970824,0.9824247,0.005637165,0.0006893946,0.001267854],"study_design_scores_gemma":[0.0006110512,0.00001017908,0.02437569,0.0001796883,0.00005039332,0.0001900094,0.002624806,0.001729775,0.9388681,0.001833947,0.02924201,0.0002843585],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8791286,0.00009828695,0.00001266089,0.00228232,0.00008390225,0.00007752021,0.0000786498,0.0000245485,0.1182135],"genre_scores_gemma":[0.9962543,0.0001640102,0.00008024801,0.0003036048,0.00006590824,0.00001415849,0.00002591655,0.00001518886,0.003076656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1171257,"threshold_uncertainty_score":0.5761692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00371277381193162,"score_gpt":0.1482149134264193,"score_spread":0.1445021396144877,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}