{"id":"W2550125281","doi":"10.1002/chem.201605351","title":"Palladium‐Catalyzed Tandem Oxidative Arylation/Olefination of Aromatic Tethered Alkenes/Alkynes","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Canada Research Chairs","keywords":"Synthon; Chemistry; Palladium; Catalysis; Tandem; Oxidative phosphorylation; Combinatorial chemistry; Organic chemistry; Materials science; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001089764,0.0002846065,0.0003287673,0.00006892281,0.0001726754,0.00006894282,0.0004326151,0.0000829883,0.007587418],"category_scores_gemma":[0.001590802,0.0002214501,0.0002074073,0.0002341354,0.0001954075,0.0002489272,0.00009306299,0.0002431206,0.00009538558],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002087939,"about_ca_system_score_gemma":0.0001652058,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001310435,"about_ca_topic_score_gemma":3.60303e-7,"domain_scores_codex":[0.9977452,0.0001594946,0.0009241934,0.0003432576,0.0005465751,0.0002812711],"domain_scores_gemma":[0.997593,0.0003962829,0.0009703877,0.0004749433,0.0003455756,0.0002197809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005347961,0.00009007736,0.001693523,0.0001119131,0.000126006,0.00003278738,0.0002304466,0.00003966293,0.9846769,0.0000207774,0.001033918,0.01189053],"study_design_scores_gemma":[0.003303075,0.00002104449,0.004441314,0.0007059388,0.0001344632,0.0007056583,0.0003855294,0.0004640857,0.9779869,0.001273096,0.01007822,0.0005006606],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9317395,0.0002129347,0.03446133,0.0004649941,0.0001701264,0.00006379036,0.00005019912,0.000108814,0.0327283],"genre_scores_gemma":[0.9859329,0.00008508978,0.003147523,0.00003056194,0.0006864119,0.000004960556,0.0001028621,0.00008182955,0.009927829],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05419342,"threshold_uncertainty_score":0.9933198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02416463903130141,"score_gpt":0.2568279738609035,"score_spread":0.2326633348296021,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}