{"id":"W2551552585","doi":"10.1039/c6qo00648e","title":"Polymerization of acetylene: polyynes, but not carbyne","year":2016,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Fullerene Chemistry and Applications","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Hospital Edmonton; University of Alberta","funders":"Deutsche Forschungsgemeinschaft","keywords":"Carbyne; Acetylene; Chemistry; Polymerization; Steric effects; Polymer chemistry; Photochemistry; Organic chemistry; Polymer; Catalysis; Carbene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001468817,0.0005339989,0.0001610125,0.0001807975,0.0002063973,0.0002817387,0.0002047945,0.0002322537,0.001765106],"category_scores_gemma":[0.0003313535,0.0001566728,0.0002413849,0.0002274271,0.000188903,0.0003870885,0.0003250706,0.0007629803,0.0008252591],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002291306,"about_ca_system_score_gemma":0.0003887174,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005598358,"about_ca_topic_score_gemma":0.001475568,"domain_scores_codex":[0.9998488,0.00001379271,0.00001476964,0.00004322659,0.00003949215,0.00003990736],"domain_scores_gemma":[0.9998257,0.00003855531,0.00004460477,0.00002894535,0.00002861878,0.00003370784],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004261033,0.00001151562,0.00006903311,0.00005864533,0.000007543244,0.00006577769,0.00002942291,0.00005333011,0.9973093,0.0004135628,0.00005778041,0.001881629],"study_design_scores_gemma":[0.00001338246,0.0001466263,0.000651578,0.000005848125,0.000007906327,0.00008878991,0.000007340797,0.0001673667,0.9963393,0.00004727141,0.00252006,0.000004448268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9704231,0.001957426,0.01492311,0.0001881266,0.0001335342,0.0001557493,0.0002858094,0.0001196173,0.01181357],"genre_scores_gemma":[0.9885153,0.001549246,0.005055353,0.00003670243,0.00001767914,0.00005125572,0.0001941534,0.0000397184,0.004540615],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001765106,"threshold_uncertainty_score":0.005904853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004872944323979988,"score_gpt":0.1831988803319995,"score_spread":0.1783259360080195,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}