{"id":"W2552140478","doi":"10.3390/ma9110921","title":"Oxygen Evolution at Manganite Perovskite Ruddlesden-Popper Type Particles: Trends of Activity on Structure, Valence and Covalence","year":2016,"lang":"en","type":"article","venue":"Materials","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Research Council Canada; Western Economic Diversification Canada; Massachusetts Department of Fish and Game; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Deutsche Forschungsgemeinschaft; Canadian Light Source","keywords":"Valence (chemistry); Oxygen evolution; Oxidation state; Rietveld refinement; Oxygen; Catalysis; Chemistry; X-ray absorption spectroscopy; Electronic structure; Covalent bond; Crystallography; Redox; Materials science; Chemical physics; Absorption spectroscopy; Crystal structure; Inorganic chemistry; Physical chemistry; Computational chemistry; Electrochemistry; Electrode; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001843627,0.0001795061,0.000246495,0.0001158026,0.00008285562,0.00001748089,0.0001479456,0.0001097656,0.0009059519],"category_scores_gemma":[0.00007422069,0.0001262286,0.00003261092,0.0001650719,0.000110371,0.0002091719,0.0001091263,0.00002976908,0.00009431689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002328899,"about_ca_system_score_gemma":0.0000196959,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003801194,"about_ca_topic_score_gemma":0.0001755188,"domain_scores_codex":[0.9987752,0.0001298272,0.0002107011,0.0003312739,0.0002729757,0.0002800302],"domain_scores_gemma":[0.9992554,0.00006729136,0.0001582352,0.0003674452,0.00008205585,0.00006953473],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004452311,0.0000221915,0.0009074063,0.00003725888,0.00002682658,0.000002697028,0.00006764239,0.00001193942,0.9893026,0.002961439,0.0001426373,0.006072121],"study_design_scores_gemma":[0.0004648967,0.0002153698,0.03957624,0.00007811934,0.00003093453,0.00001079057,0.000006885138,0.000007646712,0.9576691,0.0007894025,0.0009867902,0.0001638351],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990666,0.0000636282,0.00002308732,0.000114343,0.0002866037,0.00005128143,0.0000468457,0.00006120318,0.0002864382],"genre_scores_gemma":[0.9978414,0.00006878789,0.00005395892,0.00003332269,0.00007451789,0.000004698204,0.00001418668,0.00002676072,0.001882436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03866884,"threshold_uncertainty_score":0.9919538,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01101928068709265,"score_gpt":0.2224140770551037,"score_spread":0.211394796368011,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}