{"id":"W2553418162","doi":"10.1039/c6ob02278b","title":"Boronic esters as protective groups in carbohydrate chemistry: processes for acylation, silylation and alkylation of glycoside-derived boronates","year":2016,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation; McLean Foundation","keywords":"Chemistry; Silylation; Acylation; Phenylboronic acid; Boronic acid; Alkylation; Organic chemistry; Protecting group; Borylation; Glycoside; Ether; Catalysis; Aryl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001855517,0.0004148563,0.0004220787,0.00003730851,0.00009565899,0.00004627319,0.0002610961,0.0004256056,0.000448222],"category_scores_gemma":[0.001094524,0.0003835871,0.0001118587,0.0003610573,0.000219943,0.0002298955,0.00009537565,0.0001374882,0.000002771291],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003052457,"about_ca_system_score_gemma":0.0003435163,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003668356,"about_ca_topic_score_gemma":0.00001232659,"domain_scores_codex":[0.9979162,0.00001766404,0.0006119754,0.0007650595,0.0002630219,0.0004260531],"domain_scores_gemma":[0.9984317,0.0002309093,0.000428342,0.0004677374,0.0003010786,0.0001402381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001679823,0.00009586564,0.001483073,0.002091831,0.00008496865,0.000007224807,0.0002397669,0.000001953896,0.9946715,0.000004946626,0.000004530509,0.001146405],"study_design_scores_gemma":[0.001533998,0.00001729341,0.0003182245,0.0005033494,0.00007077993,0.00002514899,0.0002587652,0.0001115088,0.9954299,0.001193032,0.00006765954,0.0004703638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9932666,0.0007011728,0.004349742,0.0003804098,0.00001744989,0.0003001387,0.0001012024,0.00009787957,0.0007853637],"genre_scores_gemma":[0.9989946,0.0001299679,0.0001157973,0.00001147798,0.00009017228,0.000198597,0.0001537099,0.00007762291,0.0002279985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005728015,"threshold_uncertainty_score":0.9998616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005581562563627078,"score_gpt":0.2077054647203319,"score_spread":0.2021239021567048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}