{"id":"W2553839593","doi":"10.1039/c6dt04264c","title":"Pincer-plus-one ligands in self-assembly with palladium(<scp>ii</scp>): a molecular square and a molecular tetrahedron","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Tetrahedron; Pincer movement; Square (algebra); Palladium; Chemistry; Self-assembly; Stereochemistry; Crystallography; Catalysis; Mathematics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001182543,0.0002490064,0.0001871726,0.0001169738,0.00023719,0.0004889295,0.0003085212,0.0002487634,0.001223304],"category_scores_gemma":[0.0001320555,0.0002153293,0.000136147,0.0001523202,0.000250552,0.0003286507,0.0004870368,0.0004780449,0.0005063115],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001841308,"about_ca_system_score_gemma":0.0001633994,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004004198,"about_ca_topic_score_gemma":0.001078803,"domain_scores_codex":[0.9998901,0.00002360702,0.000007572124,0.00002544049,0.00001981167,0.00003348496],"domain_scores_gemma":[0.9999585,0.00001148421,0.000008440798,0.000005047744,0.000003421636,0.00001302245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004860111,0.000171218,0.0002337957,0.0004973013,0.00003418962,0.0003454482,0.0003761697,0.002788719,0.9614981,0.008464318,0.0008953505,0.02420937],"study_design_scores_gemma":[0.00003947371,0.0004487555,0.0002766098,0.000008674277,0.00001446602,0.0001289129,0.00004649494,0.002681013,0.9895313,0.0003697038,0.006436319,0.00001823321],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762787,0.001729551,0.006437143,0.0001350301,0.00009932541,0.00006729428,0.00006137343,0.0001908007,0.01500089],"genre_scores_gemma":[0.9933391,0.0005654871,0.002092547,0.00006513301,0.00001137234,0.00003317921,0.00005700676,0.00003146994,0.003804719],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001223304,"threshold_uncertainty_score":0.004092336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007164751642285989,"score_gpt":0.2094783831172075,"score_spread":0.2023136314749215,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}