{"id":"W2554726028","doi":"10.3791/55021","title":"Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)","year":2016,"lang":"en","type":"article","venue":"Journal of Visualized Experiments","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Reagent; White Phosphorus; Phosphine; Chemistry; Bromide; Phosphorus; Metathesis; Salt (chemistry); Reactivity (psychology); Inorganic chemistry; Trimethylsilyl; Potassium; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003789268,0.0004932929,0.0003260812,0.0001974283,0.0002020321,0.0004201793,0.0006758313,0.0006166259,0.001259033],"category_scores_gemma":[0.0004280946,0.0002433713,0.0002660273,0.0002474732,0.0001569476,0.0004478643,0.0004175798,0.0006972602,0.001538181],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002650753,"about_ca_system_score_gemma":0.0004452038,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003970797,"about_ca_topic_score_gemma":0.0006237241,"domain_scores_codex":[0.9996738,0.00004590355,0.00004048248,0.00006648741,0.0001371098,0.0000361051],"domain_scores_gemma":[0.9998206,0.00002450394,0.00004716894,0.00003270514,0.00004620877,0.00002878146],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003860675,0.00001554516,0.00008475299,0.0001087995,0.000009424393,0.0001592629,0.00003002129,0.0003123301,0.994561,0.0002153472,0.00009512529,0.004369856],"study_design_scores_gemma":[0.000007858424,0.00009166063,0.00009669629,0.000003004413,0.000007618246,0.0001801506,0.000004384857,0.0003084858,0.9973134,0.00003101039,0.001949514,0.000006158345],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9080538,0.002916436,0.07593916,0.0004585691,0.0001440188,0.0003476191,0.001510576,0.0005480919,0.01008178],"genre_scores_gemma":[0.9162443,0.003212984,0.07357599,0.0001156744,0.00004370087,0.0001877739,0.001458687,0.0002707099,0.004890202],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001259033,"threshold_uncertainty_score":0.004211843,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02232411498294094,"score_gpt":0.3917693466095116,"score_spread":0.3694452316265706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}