{"id":"W2555224455","doi":"10.1021/acs.orglett.6b01687","title":"Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes","year":2016,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Center for Selective C-H Functionalization, National Science Foundation; Resnick Sustainability Institute for Science, Energy and Sustainability, California Institute of Technology; Dow Chemical Company","keywords":"Chemistry; Catalysis; Reagent; Silylation; Silyl ether; Sodium hydroxide; Salt (chemistry); Stoichiometry; Alcohol; Combinatorial chemistry; Molecule; Hydroxide; Coupling (piping); Coupling reaction; Organic chemistry; Polymer chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001613277,0.0005391573,0.0002032025,0.0002276798,0.0002134037,0.0001503925,0.0003963363,0.0001651661,0.001645468],"category_scores_gemma":[0.0001078591,0.0002084822,0.0002650885,0.0001494318,0.0001748428,0.0003298476,0.0003263275,0.000558059,0.0008501027],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002376457,"about_ca_system_score_gemma":0.0002980036,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003513994,"about_ca_topic_score_gemma":0.001187694,"domain_scores_codex":[0.9998878,0.00001168221,0.00001269987,0.00002284647,0.00003049793,0.00003430878],"domain_scores_gemma":[0.999948,0.000006524677,0.00001485921,0.000009614565,0.00000987947,0.00001108163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005041981,0.00002736865,0.00008740364,0.0001047167,0.000008589792,0.0001336369,0.00004783728,0.0001982089,0.9928153,0.0004955854,0.0001666076,0.005864387],"study_design_scores_gemma":[0.000004898438,0.00007005145,0.000190451,0.000002863874,0.00000542901,0.00007813686,0.000009574182,0.0001522196,0.9955248,0.00006312563,0.003894246,0.000004267742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9192231,0.004242907,0.0563761,0.000343799,0.0002341576,0.0002799578,0.0008038043,0.0006493406,0.01784675],"genre_scores_gemma":[0.9726381,0.003503755,0.01519974,0.0001131474,0.00004288102,0.00008032436,0.0006379969,0.00009529826,0.007688669],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001645468,"threshold_uncertainty_score":0.005504668,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007839360865224767,"score_gpt":0.2153768297274065,"score_spread":0.2075374688621817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}