{"id":"W2556681983","doi":"10.1039/c6cc08512a","title":"Ultrafast chiral separations for high throughput enantiopurity analysis","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":134,"is_retracted":false,"has_abstract":true,"ca_institutions":"Process Research Ortech (Canada)","funders":"","keywords":"Bioanalysis; Supercritical fluid; Supercritical fluid chromatography; Chemistry; Chromatography; Enantioselective synthesis; Throughput; Chiral stationary phase; Ultrashort pulse; Biological fluids; Combinatorial chemistry; High-performance liquid chromatography; Organic chemistry; Computer science; Catalysis; Physics; Laser","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000089652,0.000192102,0.0003229188,0.00005164267,0.0003126754,0.00003907126,0.001077456,0.0001933124,0.0006895301],"category_scores_gemma":[0.0002202519,0.0001453702,0.0004798368,0.000555974,0.0005143114,0.0001295914,0.0001974764,0.000181798,0.00003391222],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006184204,"about_ca_system_score_gemma":0.00004014045,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001287413,"about_ca_topic_score_gemma":0.00001186285,"domain_scores_codex":[0.9987614,0.00001613097,0.0004182105,0.0003397711,0.0001535014,0.0003109695],"domain_scores_gemma":[0.9969075,0.00067738,0.0001262429,0.001993985,0.0001315462,0.000163313],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002614473,0.0004613542,0.004117142,0.00005606622,0.0009462629,3.311272e-7,0.00006434676,0.000001769071,0.9449425,0.04767096,0.001159376,0.0005537508],"study_design_scores_gemma":[0.0006321254,0.000006631118,0.0002390489,0.00003349649,0.0008856059,0.000002661058,0.00005433358,0.000282337,0.970166,0.01492296,0.01245671,0.0003181405],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8577209,0.0003314728,0.03757681,0.01149672,0.00003874401,0.0002407108,0.001614053,0.0006543748,0.09032623],"genre_scores_gemma":[0.9933696,0.0001140787,0.003766297,0.000080782,0.00009703382,0.0001587569,0.0006874761,0.00001843628,0.00170752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1356487,"threshold_uncertainty_score":0.7549871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02521859727513405,"score_gpt":0.2921377861901603,"score_spread":0.2669191889150263,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}