{"id":"W2558477886","doi":"10.1021/acs.organomet.6b00757","title":"Alkene Insertions into a Ru–PR<sub>2</sub> Bond","year":2016,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Chemistry; Alkene; Cycloaddition; Isomerization; Migratory insertion; Hydride; Photochemistry; Reductive elimination; Medicinal chemistry; Double bond; Metallacycle; Stereochemistry; Organic chemistry; Catalysis; X-ray crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002151801,0.0004392854,0.0005531028,0.0002323397,0.0002781159,0.000112615,0.0006649,0.0002190482,0.03019036],"category_scores_gemma":[0.0003028668,0.0003306431,0.000383595,0.0007767158,0.0002141835,0.0003266128,0.0003216403,0.0001736505,0.002383668],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002328399,"about_ca_system_score_gemma":0.0001216859,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002190784,"about_ca_topic_score_gemma":0.00009228452,"domain_scores_codex":[0.997531,0.00002666984,0.0006145483,0.0007378903,0.0004872718,0.0006026155],"domain_scores_gemma":[0.997832,0.0002137071,0.0002184934,0.001264054,0.0001296651,0.0003421055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001309456,0.0002103401,0.0005485024,0.00004415264,0.0002179712,0.00001109439,0.0001161786,3.16852e-7,0.8779436,0.001245833,0.0003912822,0.1192576],"study_design_scores_gemma":[0.0005138269,0.00002138658,0.001452507,0.00004790133,0.0001992289,0.00002325627,0.00008957844,0.000008830753,0.8334851,0.001991054,0.1616086,0.0005588101],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9782681,0.0005568276,0.0009682867,0.001728462,0.0001218878,0.00008310904,0.00008099878,0.0003112197,0.01788114],"genre_scores_gemma":[0.9918442,0.0005170169,0.0005818938,0.0001873271,0.0003265129,0.00005934922,0.00006033801,0.0001228406,0.006300466],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1612173,"threshold_uncertainty_score":0.9999146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009814957648224001,"score_gpt":0.2023947056777633,"score_spread":0.1925797480295393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}