{"id":"W2560096417","doi":"10.1126/science.aaf7229","title":"The broadening reach of frustrated Lewis pair chemistry","year":2016,"lang":"en","type":"review","venue":"Science","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1223,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Frustrated Lewis pair; Chemistry; Lewis acids and bases; Catalysis; Molecule; Transition metal; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000735345,0.0004967331,0.0005122764,0.0009491493,0.0004174527,0.001164023,0.0005065618,0.000810638,0.002567205],"category_scores_gemma":[0.000480583,0.000218069,0.0002309661,0.0007531336,0.0009711703,0.002174689,0.0009369628,0.001955847,0.001012939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009197092,"about_ca_system_score_gemma":0.001011313,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006432661,"about_ca_topic_score_gemma":0.0009936994,"domain_scores_codex":[0.9997857,0.00005267183,0.00001421849,0.00003840613,0.00008307918,0.00002593361],"domain_scores_gemma":[0.9998072,0.0001089471,0.00001633468,0.00001135641,0.0000369041,0.00001925509],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0000619967,0.00007214295,0.0002077922,0.009673494,0.0000661337,0.0004712552,0.0004514537,0.001278468,0.01545046,0.2442845,0.02230748,0.7056748],"study_design_scores_gemma":[0.000006465654,0.00006008022,0.0001546885,0.0006094318,0.00001255845,0.0006439047,0.00006863962,0.0002951687,0.00410044,0.02109224,0.9729401,0.00001611819],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.001173581,0.9828678,0.001994762,0.001272751,0.0002605613,0.000005632624,0.00002065382,0.00002436748,0.01237981],"genre_scores_gemma":[0.0238038,0.9692624,0.001518506,0.000717911,0.0003427528,0.00001866294,0.00003053871,0.000007853206,0.00429758],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.002567205,"threshold_uncertainty_score":0.008588135,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02761705287291166,"score_gpt":0.3092116838647168,"score_spread":0.2815946309918052,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}