{"id":"W2560180892","doi":"10.1016/j.gca.2016.11.043","title":"Soluble Mn(III)–L complexes are abundant in oxygenated waters and stabilized by humic ligands","year":2016,"lang":"en","type":"article","venue":"Geochimica et Cosmochimica Acta","topic":"Geochemistry and Elemental Analysis","field":"Earth and Planetary Sciences","cited_by":191,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Delaware; National Science Foundation","keywords":"Biogeochemical cycle; Chemistry; Manganese; Redox; Environmental chemistry; Metal; Biomineralization; Colloid; Inorganic chemistry; Organic chemistry; Geology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004133553,0.0003577028,0.0005021731,0.0001374844,0.0002221625,0.000116409,0.0003983138,0.0001341127,0.002113189],"category_scores_gemma":[0.00005522198,0.000245679,0.0001124954,0.0003071141,0.0002595018,0.0003350748,0.00008107488,0.0002248143,0.00008021861],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001978427,"about_ca_system_score_gemma":0.00004376828,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001324535,"about_ca_topic_score_gemma":0.003320964,"domain_scores_codex":[0.9976488,0.000102609,0.0005026282,0.0006848727,0.0003170396,0.0007440443],"domain_scores_gemma":[0.9989215,0.0002107989,0.000188444,0.0003607198,0.0000420869,0.0002764084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005178908,0.0001898222,0.223087,0.00007259277,0.0001544809,0.00002129243,0.000517791,0.00002369123,0.7517803,0.00001934006,0.02080765,0.002808214],"study_design_scores_gemma":[0.00974733,0.0004707521,0.3901849,0.0004908193,0.0002262348,0.0001087791,0.001882689,0.00236789,0.5558715,0.008584798,0.02756976,0.002494477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909816,0.0001790782,0.000007245765,0.006895729,0.0001006009,0.0002044493,0.0006314229,0.00008193044,0.0009179823],"genre_scores_gemma":[0.9972164,0.0005025874,0.0001150877,0.0006117153,0.00002798936,0.000005964998,0.0007470488,0.0000103994,0.000762788],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1959087,"threshold_uncertainty_score":0.9999995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00888367171546385,"score_gpt":0.2031966912094988,"score_spread":0.1943130194940349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}