{"id":"W2560200544","doi":"10.1021/acs.joc.6b02733","title":"Phase-Transfer Catalyzed <i>O</i>-Silyl Ether Deprotection Mediated by a Cyclopropenium Cation","year":2016,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Silylation; Taft equation; Catalysis; Silyl ether; Ether; Density functional theory; Silyl enol ether; Molecule; Computational chemistry; Phase (matter); Atoms in molecules; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001165003,0.0004821362,0.0001923677,0.0001141684,0.0001468014,0.0001611449,0.0003673119,0.0002791444,0.00243917],"category_scores_gemma":[0.0001679926,0.0001309234,0.0001789679,0.0001109755,0.0001860864,0.0002782038,0.0002077921,0.0005466635,0.0007543683],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001576494,"about_ca_system_score_gemma":0.0002015231,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002916285,"about_ca_topic_score_gemma":0.0005184984,"domain_scores_codex":[0.999943,0.000005256597,0.000003681407,0.00001415599,0.00001305193,0.0000208796],"domain_scores_gemma":[0.9999492,0.00001420831,0.00001808778,0.000007540913,0.000006095837,0.00000480263],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007876609,0.00002736117,0.00008820063,0.0001823874,0.00000807831,0.000240263,0.00002734254,0.0003264346,0.9926042,0.001165884,0.0004320203,0.004819],"study_design_scores_gemma":[0.00000723826,0.00008182081,0.0001382333,0.000003391967,0.000004327359,0.00006686757,0.000004241548,0.0004279998,0.9972253,0.00006162244,0.001975291,0.000003682746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9549943,0.00151863,0.02343701,0.0003448403,0.000275147,0.0001304486,0.0006567176,0.0004082479,0.01823469],"genre_scores_gemma":[0.991137,0.001045465,0.004491765,0.00008750673,0.00002725265,0.0000372207,0.0002502396,0.00003750768,0.002885883],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00243917,"threshold_uncertainty_score":0.008159816,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004755068468895426,"score_gpt":0.2157269716924836,"score_spread":0.2109719032235882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}