{"id":"W2561083499","doi":"10.1021/acsomega.6b00335","title":"Sultam-Based Hetero[5]helicene: Synthesis, Structure, and Crystallization-Induced Emission Enhancement","year":2016,"lang":"en","type":"article","venue":"ACS Omega","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation; University of California, Riverside; University of Ottawa","keywords":"Helicene; Crystallization; Fluorophore; Materials science; Photochemistry; Nanotechnology; Molecule; Chemistry; Organic chemistry; Fluorescence; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007089071,0.0001388666,0.0000944992,0.00007921407,0.0001169817,0.0001387796,0.0001386675,0.0001341987,0.0005696014],"category_scores_gemma":[0.00007835707,0.00006802341,0.00007440359,0.00009373937,0.0001141801,0.0001585218,0.0001019336,0.0001458633,0.0001369685],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002654965,"about_ca_system_score_gemma":0.000193175,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001186137,"about_ca_topic_score_gemma":0.00278299,"domain_scores_codex":[0.9999552,0.000006266369,0.000002392683,0.000009586828,0.00001370032,0.00001288009],"domain_scores_gemma":[0.9999621,0.000005225847,0.000009935185,0.000005169646,0.000009027973,0.000008519363],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002237154,0.000005639331,0.00004890654,0.00001186974,0.00000142468,0.00003526596,0.00001275031,0.00009597937,0.9984047,0.0001655837,0.00001747901,0.001178062],"study_design_scores_gemma":[0.000002889766,0.00004284126,0.000358994,8.685682e-7,0.000002161474,0.00004634706,0.000005792292,0.0002867048,0.9984338,0.00001647576,0.000801404,0.000001832403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9882626,0.0005443403,0.006056105,0.00004401536,0.000006608587,0.00005387302,0.0002413574,0.00005331026,0.004737793],"genre_scores_gemma":[0.9923401,0.0003947728,0.005318088,0.00001769576,0.000002245841,0.00001926783,0.0001852205,0.00001329116,0.001709379],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001186137,"threshold_uncertainty_score":0.002358437,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01575114515338242,"score_gpt":0.2262851941747698,"score_spread":0.2105340490213874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}