{"id":"W2561083499","doi":"10.1021/acsomega.6b00335","title":"Sultam-Based Hetero[5]helicene: Synthesis, Structure, and Crystallization-Induced Emission Enhancement","year":2016,"lang":"en","type":"article","venue":"ACS Omega","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation; University of California, Riverside; University of Ottawa","keywords":"Helicene; Crystallization; Fluorophore; Materials science; Photochemistry; Nanotechnology; Molecule; Chemistry; Organic chemistry; Fluorescence; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001019934,0.0002207553,0.0002310818,0.00004717643,0.0001498718,0.00007588942,0.0002310219,0.0001251102,0.000885542],"category_scores_gemma":[0.0003442592,0.0001390845,0.00004711782,0.00006283838,0.00005015979,0.0001317094,0.00007694618,0.00005924538,0.00001625616],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006868813,"about_ca_system_score_gemma":0.00005161814,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001872117,"about_ca_topic_score_gemma":0.000005685488,"domain_scores_codex":[0.9987618,0.00002783366,0.0003057359,0.0003473757,0.0002890598,0.0002681986],"domain_scores_gemma":[0.9987991,0.0004112437,0.0001257695,0.0004656771,0.00006927758,0.0001289417],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004813238,0.0000389113,0.001257173,0.00009614093,0.00003102524,0.000001755197,0.00004568711,5.986893e-7,0.950897,0.0000249701,0.0005392932,0.04701928],"study_design_scores_gemma":[0.000465326,0.00002731358,0.0003586099,0.0003837297,0.00002569855,0.000003652086,0.00002597927,0.00007366751,0.9826674,0.0002204827,0.01549921,0.0002488554],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957874,0.0002355912,0.0002557803,0.001150091,0.00007227358,0.00007082465,0.00002353745,0.00007956071,0.002324971],"genre_scores_gemma":[0.9980639,0.00007792263,0.0005037755,0.0001335287,0.0001027755,0.0000309418,0.000008316178,0.00003186296,0.001047023],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04677043,"threshold_uncertainty_score":0.9696064,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01575114515338242,"score_gpt":0.2262851941747698,"score_spread":0.2105340490213874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}