{"id":"W2561139824","doi":"10.1021/jacs.6b12114","title":"Alkali Metal-Hydroxide-Catalyzed C(<i>sp</i>)–H Bond silylation","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":102,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Resnick Sustainability Institute for Science, Energy and Sustainability, California Institute of Technology; Dow Chemical Company; Bristol-Myers Squibb","keywords":"Chemistry; Catalysis; Silylation; Alkyne; Alkali metal; Combinatorial chemistry; Hydroxide; Surface modification; Scope (computer science); Triple bond; Organic chemistry; Double bond; Physical chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001794265,0.0005162221,0.0002800102,0.0002400915,0.0002891967,0.0003111342,0.0004149214,0.0003181151,0.00317325],"category_scores_gemma":[0.000122781,0.0002885619,0.0003167846,0.0001314623,0.0003063938,0.0004462666,0.0003163576,0.0005550573,0.0008634519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003320258,"about_ca_system_score_gemma":0.0004535308,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004853404,"about_ca_topic_score_gemma":0.0010069,"domain_scores_codex":[0.9998653,0.00001320764,0.00001050838,0.00002632055,0.00005013886,0.00003455],"domain_scores_gemma":[0.9999652,0.00000408656,0.00001040112,0.000007680752,0.000006796156,0.000005820977],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006116425,0.00002499253,0.0001528008,0.0001613941,0.00001268032,0.0001633131,0.00003065824,0.0002842774,0.9839311,0.002155164,0.0008290671,0.01219354],"study_design_scores_gemma":[0.000006535253,0.00006315441,0.0002236688,0.000003176789,0.000007438183,0.0002423885,0.00001364183,0.0004101467,0.9922518,0.0001729189,0.006597119,0.000007979929],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8555595,0.005841535,0.06466112,0.001489787,0.0008255693,0.000309951,0.001416703,0.001497743,0.06839813],"genre_scores_gemma":[0.9851854,0.001679881,0.007985752,0.0001046014,0.00005609178,0.00003504982,0.0003124177,0.00003578238,0.004604944],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00317325,"threshold_uncertainty_score":0.01061565,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01567233760475978,"score_gpt":0.2736969289262527,"score_spread":0.258024591321493,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}