{"id":"W2563295566","doi":"10.1021/acs.macromol.6b02320","title":"End-Capping Strategies for Triggering End-to-End Depolymerization of Polyglyoxylates","year":2016,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Depolymerization; End-to-end principle; Polymer; Chemistry; Molar mass; Materials science; Polymer chemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002424935,0.0006134426,0.0001897339,0.0002027658,0.0001267957,0.0002364941,0.0002439575,0.0002870103,0.0006892837],"category_scores_gemma":[0.0002217054,0.0001947234,0.0002448203,0.0001201204,0.0001769419,0.0003855564,0.0002213879,0.0005818926,0.0002945794],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001871658,"about_ca_system_score_gemma":0.0001388061,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002186157,"about_ca_topic_score_gemma":0.0005357058,"domain_scores_codex":[0.9998242,0.00003667646,0.00001676348,0.00004125986,0.00004663158,0.00003441119],"domain_scores_gemma":[0.9998517,0.00003215644,0.00005578141,0.00001672906,0.00001930829,0.00002426363],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001923452,0.00001183746,0.0000232411,0.00003682132,0.000002707394,0.00003931934,0.00001236524,0.0001168301,0.9983296,0.0001084914,0.00001677255,0.001282804],"study_design_scores_gemma":[0.00000212602,0.00006460213,0.0001408176,0.000002321127,0.000003402127,0.00002813077,0.000002678599,0.0003383456,0.9987054,0.00001399307,0.0006957321,0.000002360782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9338372,0.003527443,0.05811907,0.0001154374,0.0001056551,0.0001744827,0.0002141137,0.0002600429,0.00364658],"genre_scores_gemma":[0.960205,0.002116663,0.0345924,0.00009991398,0.00002744617,0.00008252732,0.0002297335,0.00005963639,0.002586562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006892837,"threshold_uncertainty_score":0.002305925,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01195274046643794,"score_gpt":0.2411849645643961,"score_spread":0.2292322240979582,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}