{"id":"W2563796185","doi":"10.1021/jacs.6b11454","title":"{Fe(NO)<sub>2</sub>}<sup>9</sup> Dinitrosyl Iron Complex Acting as a Vehicle for the NO Radical","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Ministry of Science and Technology, Taiwan","keywords":"Chemistry; Electron paramagnetic resonance; Ligand (biochemistry); Crystallography; Radical; Atomic orbital; Cationic polymerization; Ligand field theory; Bent molecular geometry; Molecular orbital; Stereochemistry; Nuclear magnetic resonance; Electron; Molecule; Ion; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001218697,0.0001993387,0.0001136747,0.00004870664,0.0000963034,0.0001531399,0.0002130986,0.0001990827,0.001373743],"category_scores_gemma":[0.0001324742,0.0000728478,0.0000368713,0.00003836614,0.0001433762,0.0001427336,0.0001542317,0.0002008341,0.0003176175],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001844179,"about_ca_system_score_gemma":0.00008120139,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002022411,"about_ca_topic_score_gemma":0.0004981392,"domain_scores_codex":[0.9999472,0.000009775245,0.00000389268,0.00001392045,0.0000156793,0.00000938548],"domain_scores_gemma":[0.9999306,0.00001413643,0.00002143558,0.000007139719,0.00001359195,0.0000130822],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008229182,0.000007067733,0.000138232,0.0000503819,0.000002891508,0.00002975431,0.000007849596,0.00005751402,0.9978359,0.0004645206,0.00009545917,0.001228051],"study_design_scores_gemma":[0.000009355394,0.0001180606,0.0009438809,0.000005107973,0.000005435678,0.0001959965,0.00001560773,0.0009008194,0.9912059,0.0001113342,0.006485319,0.000003178517],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9800999,0.001235204,0.01176741,0.0001921106,0.00008370694,0.00004526473,0.0001453663,0.0001237821,0.006307334],"genre_scores_gemma":[0.9880904,0.0003068389,0.00753879,0.000125294,0.00001359725,0.00002454934,0.0001886804,0.00003572229,0.003676225],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001373743,"threshold_uncertainty_score":0.004595637,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01915911837258382,"score_gpt":0.2699215523436079,"score_spread":0.250762433971024,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}