{"id":"W2565819821","doi":"10.1039/c6cc07331j","title":"Carbodiimide insertion into sulfonimides: one-step route to azepine derivatives via a two-atom saccharin ring expansion","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; McGill University; International Centre for Diffraction Data","keywords":"Azepine; Carbodiimide; Saccharin; Ring (chemistry); Chemistry; Atom (system on chip); Polymer chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001537417,0.0005612313,0.000204925,0.0002116265,0.0001381749,0.000141101,0.0003902228,0.0002087459,0.001488226],"category_scores_gemma":[0.0001504886,0.0001484917,0.0001486234,0.0001867375,0.0002969698,0.0003262653,0.0002734931,0.0004789367,0.0005238456],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004743709,"about_ca_system_score_gemma":0.0004588097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008422189,"about_ca_topic_score_gemma":0.00169524,"domain_scores_codex":[0.9999056,0.00000863994,0.000008232747,0.00002631124,0.00002496283,0.00002626812],"domain_scores_gemma":[0.9999293,0.00001004061,0.00001792832,0.00001424849,0.000008405505,0.00002009363],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000119987,0.00007172222,0.0001285563,0.0001126691,0.00000795766,0.0002364813,0.00008280883,0.0003688511,0.990221,0.00149981,0.0002401918,0.006910054],"study_design_scores_gemma":[0.00002722253,0.0002401765,0.0006743239,0.000004033719,0.000006879606,0.0001865448,0.00001137258,0.000505008,0.993023,0.00006681109,0.005243334,0.0000111527],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9578367,0.001369451,0.02402573,0.0002545889,0.0001021685,0.000299434,0.0005066892,0.0005142671,0.01509087],"genre_scores_gemma":[0.9818703,0.001035755,0.01206304,0.00004505441,0.00001766689,0.00007427118,0.0002266313,0.00003989784,0.004627337],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001488226,"threshold_uncertainty_score":0.004978657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04169988086642463,"score_gpt":0.2947814073732775,"score_spread":0.2530815265068528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}