{"id":"W2567627304","doi":"10.13179/canchemtrans.2015.03.04.0239","title":"Oxidation of N,-diphenylnitrones by N-chlorosuccinimide in alkaline medium – A non-linear Hammett plot","year":2016,"lang":"en","type":"article","venue":"Canadian Chemical Transactions","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hammett equation; Chemistry; Environmental chemistry; Plot (graphics); Mathematics; Kinetics; Statistics; Reaction rate constant; Physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007224175,0.0002040678,0.0002867664,0.00009196663,0.00005008082,0.000007142529,0.0002493038,0.0002822901,0.009171311],"category_scores_gemma":[0.00006857384,0.0001831576,0.0001091983,0.0002642187,0.000154031,0.0001128571,0.000005440687,0.0002194166,0.00005233285],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004181095,"about_ca_system_score_gemma":0.0003611408,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01194701,"about_ca_topic_score_gemma":0.01286596,"domain_scores_codex":[0.9986163,0.000006218886,0.0004344952,0.0003299867,0.0001742419,0.0004386931],"domain_scores_gemma":[0.9989952,0.000107569,0.00007622482,0.0003184496,0.00006730038,0.0004352751],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001899192,0.00006405437,0.0002703856,0.00006284341,0.00003672923,0.000005103116,0.00008489691,0.000001403181,0.9979782,0.000007998079,0.0006007561,0.0008686974],"study_design_scores_gemma":[0.0009339538,0.000005177127,0.00004898502,0.00007393287,0.00003738598,0.00001208513,0.0000980921,0.00003254168,0.9848956,0.00005900031,0.01357772,0.0002255447],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889944,0.00006859332,0.004526396,0.00186234,0.00007661841,0.00007099112,0.0006234727,0.00004882315,0.003728434],"genre_scores_gemma":[0.9969077,0.00004862681,0.0003252853,0.0000991648,0.0001147632,0.00002468305,0.000126213,0.0000405945,0.002312938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01308256,"threshold_uncertainty_score":0.9946325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007692036918762234,"score_gpt":0.2031034230268781,"score_spread":0.1954113861081159,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}