{"id":"W2571002908","doi":"10.1002/anie.201611196","title":"Trapping Rare and Elusive Phosphinidene Chalcogenides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council","keywords":"Phosphinidene; Reactivity (psychology); Chemistry; Selenide; Monomer; Trapping; Sulfide; Carbene; Photochemistry; Organic chemistry; Catalysis; Polymer; Selenium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001274156,0.0002140059,0.0001648324,0.0001532086,0.0001684175,0.0003778945,0.000303668,0.0002164836,0.00138612],"category_scores_gemma":[0.0001281477,0.0001070245,0.00008914134,0.0001214433,0.0002929301,0.0002624369,0.0003975605,0.0002724241,0.0003375327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003092466,"about_ca_system_score_gemma":0.0002274017,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002958217,"about_ca_topic_score_gemma":0.0006658635,"domain_scores_codex":[0.9999175,0.0000121268,0.00000436853,0.00001741199,0.00002408454,0.00002444567],"domain_scores_gemma":[0.9999372,0.00001202319,0.00001941897,0.00001042259,0.000009667595,0.00001128463],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009074213,0.00001782392,0.0001727801,0.0001221314,0.000008973795,0.0002122344,0.00007401779,0.0004649024,0.992512,0.002555922,0.0001936262,0.003574876],"study_design_scores_gemma":[0.00001285711,0.0001111995,0.0002074289,0.000003020131,0.000005446837,0.00008839282,0.00001844238,0.0007462215,0.996632,0.0001353737,0.002034603,0.000005005545],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9854648,0.001116883,0.005075559,0.000117052,0.00003234018,0.00002722308,0.0001610625,0.000117864,0.007887281],"genre_scores_gemma":[0.9951124,0.0003492942,0.002039828,0.00001793233,0.000005109184,0.00001060235,0.00006267504,0.00001327655,0.002388888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00138612,"threshold_uncertainty_score":0.004637003,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02194262768994444,"score_gpt":0.2567715245679884,"score_spread":0.234828896878044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}