{"id":"W2571002908","doi":"10.1002/anie.201611196","title":"Trapping Rare and Elusive Phosphinidene Chalcogenides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council","keywords":"Phosphinidene; Reactivity (psychology); Chemistry; Selenide; Monomer; Trapping; Sulfide; Carbene; Photochemistry; Organic chemistry; Catalysis; Polymer; Selenium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009516592,0.0001617278,0.000157453,0.00004835693,0.0004191937,0.0003306995,0.0003787768,0.0001034704,0.005537224],"category_scores_gemma":[0.0003235789,0.0001686607,0.00007571668,0.0000223072,0.0001033159,0.000550999,0.000141998,0.0001329973,0.00002504128],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007305458,"about_ca_system_score_gemma":0.00002457936,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002766009,"about_ca_topic_score_gemma":0.000005908474,"domain_scores_codex":[0.9990473,0.00000399173,0.0002304491,0.0003011152,0.0002710029,0.000146117],"domain_scores_gemma":[0.9990926,0.00007193336,0.0002908705,0.0002974848,0.0001689641,0.00007818302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000238086,0.00005273665,0.001888007,0.00002708221,0.0001091146,0.00001128687,0.0001924499,2.622418e-7,0.9922463,0.0003750526,0.001144057,0.003929787],"study_design_scores_gemma":[0.0004336561,0.000005779963,0.01263326,0.00009488159,0.00002368404,0.00003945641,0.0001483122,0.00004975087,0.9534827,0.0004861309,0.03241158,0.0001907468],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9232929,0.0001864759,0.0006893718,0.005143828,0.001087665,0.00005717607,0.0001932487,0.0001145938,0.06923474],"genre_scores_gemma":[0.9942814,0.0003840909,0.00008858665,0.0001954065,0.002110907,0.00002143085,0.0003328377,0.00002388691,0.002561497],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07098845,"threshold_uncertainty_score":0.9953719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02194262768994444,"score_gpt":0.2567715245679884,"score_spread":0.234828896878044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}