{"id":"W2573791505","doi":"10.1021/acs.accounts.6b00441","title":"A Grand Avenue to Au Nanocluster Electrochemiluminescence","year":2017,"lang":"en","type":"article","venue":"Accounts of Chemical Research","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":237,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University; Canada Foundation for Innovation; Ontario Innovation Trust","keywords":"Electrochemiluminescence; Nanoclusters; Photoluminescence; Electrochemistry; Nanomaterials; Chemiluminescence; Materials science; Nanocrystal; Excited state; Chemistry; Electrode; Nanotechnology; Optoelectronics; Physical chemistry; Physics; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001052488,0.00009796856,0.0001930119,0.00006790892,0.0003153296,0.000179288,0.001579737,0.00008325891,0.0001848418],"category_scores_gemma":[0.001517879,0.00008474225,0.00004833929,0.000124767,0.0003782418,0.000197972,0.000600329,0.0001553849,0.0004379681],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008860115,"about_ca_system_score_gemma":0.0001631319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002545279,"about_ca_topic_score_gemma":0.00002035433,"domain_scores_codex":[0.9981577,0.00002913924,0.0002194506,0.0003587245,0.0007028697,0.000532083],"domain_scores_gemma":[0.9981064,0.0002224376,0.00008614891,0.001054406,0.0003631448,0.0001674128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005325646,0.00005662765,0.0003643468,0.00002765861,0.000002276048,0.000001037871,0.0001240363,7.065294e-8,0.9928654,0.0002267926,0.004708957,0.001569527],"study_design_scores_gemma":[0.0001706173,0.00002084259,0.0006886066,0.00006275488,0.000003019706,0.000002109203,0.00001218433,0.000007735059,0.9904748,0.0006099725,0.007855605,0.0000917081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923047,0.00002862612,0.00007294708,0.002245613,0.00004953627,0.0002403305,0.00002017235,0.00001229979,0.005025783],"genre_scores_gemma":[0.998325,0.000006357714,0.0007469032,0.00006654656,0.0001859318,0.0001070009,0.000001749051,0.00001390927,0.0005466353],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006020274,"threshold_uncertainty_score":0.5629339,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.070185044086666,"score_gpt":0.4010651082158108,"score_spread":0.3308800641291448,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}