{"id":"W2577296200","doi":"10.1021/acscatal.6b02590","title":"STM Study of Ketopantolactone/(<i>R</i>)-1-(1-Naphthyl)ethylamine Complexes on Pt(111): Comparison of Prochiral and Enantiomeric Ratios and Examination of the Contribution of CH···OC Bonding","year":2017,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Lundbeckfonden; Danmarks Frie Forskningsfond; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Foundation for Innovation","keywords":"Chemistry; Ethylamine; Diastereomer; Enantiomer; Molecule; Stereospecificity; Stereochemistry; Catalysis; Crystallography; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003242462,0.0001600115,0.0006058497,0.0001043878,0.0001258443,0.00001827262,0.0002321679,0.00006573165,0.000003841506],"category_scores_gemma":[0.0002127771,0.000129738,0.0000702875,0.0002516152,0.0002160828,0.0001724242,0.00009435866,0.00009427402,1.617843e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002089375,"about_ca_system_score_gemma":0.000008841175,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001126781,"about_ca_topic_score_gemma":0.00007272592,"domain_scores_codex":[0.9988119,0.00004696358,0.0005503436,0.0001817453,0.0002861254,0.000122948],"domain_scores_gemma":[0.9985309,0.0001430223,0.0006172418,0.000533291,0.0001463861,0.00002915819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003963593,0.0003096084,0.1298296,0.000259994,0.000295675,2.78157e-7,0.002427727,0.0005713999,0.8641414,0.00003289445,0.000007706917,0.002084125],"study_design_scores_gemma":[0.000637934,0.0001183043,0.2694017,0.00005831692,0.0002735185,8.811616e-7,0.001660997,0.001190251,0.7265598,0.000007742654,0.00000368693,0.00008683513],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991173,0.0003330323,0.00005724312,0.00001496834,0.00003165927,0.0002586075,0.00004030855,0.00001277931,0.000134149],"genre_scores_gemma":[0.9998297,0.00003207699,0.00001887382,9.736594e-7,0.00001005617,0.00001075295,0.00006186702,0.00001153764,0.00002413467],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1395721,"threshold_uncertainty_score":0.5290564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0161604640213889,"score_gpt":0.2613067806295034,"score_spread":0.2451463166081145,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}